Hidrogel Superabsorben Berbasis Natrium Alginat-Bentonit sebagai Pelapis Pupuk Lepas Lambat

Sintia Lestari, L. M. Yuningsih, S. Muharam
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Abstract

The application of slow-release fertilizer in agriculture is currently very necessary because of its performance that can control the release of fertilizer. However, the case of excessive use of urea on agricultural land has the potential to cause water pollution because the process of nitrification produces nitrite ions that are toxic and eutrophication of water and prevent harmful N2O gas emissions. This research has been done making urea slow-release fertilizer in the form of superabsorbent hydrogel with crosslink method and bentonite coating technique by sodium alginate. The hydrogels formed characterized its structure and morphology with FTIR and SEM-EDS, as well as swelling tests to see its ability to store water. Furthermore, to test the performance of hydrogel as a slow-release fertilizer is carried out urea release test at various pH and times. The results showed that urea fertilizer has filled the structure and surface of hydrogel with a swelling ratio of 2.894,30% (BAC1) and 3.428,52% (BAC2). The addition of CaCl2 crosslinking agent provides increased gelation power, swelling, and adsorption capacity against urea in addition to the urea release process is not affected by pH.
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水凝胶,高压氧钠,作为一种缓慢的自由流动肥料涂料
缓释肥料具有控制肥料释放的性能,因此在农业中应用是十分必要的。然而,在农业用地上过量使用尿素的情况有可能造成水污染,因为硝化过程产生的亚硝酸盐离子是有毒的,并使水富营养化,防止有害的N2O气体排放。以海藻酸钠为原料,采用交联法和膨润土包覆法制备高吸水性水凝胶形式的尿素缓释肥料。所形成的水凝胶通过FTIR和SEM-EDS表征了其结构和形态,并通过膨胀测试来观察其储水能力。此外,为了测试水凝胶作为缓释肥料的性能,进行了不同pH值和不同时间的尿素释放试验。结果表明:尿素肥填充了水凝胶的结构和表面,溶胀率分别为2.894.30% (BAC1)和3.428.52% (BAC2);CaCl2交联剂的加入增加了凝胶力、溶胀和对尿素的吸附能力,并且尿素的释放过程不受pH值的影响。
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