Roli Verma, Kirti Srivastava, R. Jagadish, Rama Dubey
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引用次数: 0
Abstract
Anisotropic polymerization of 5-hydroxy isophthalic acid and isophthalic acid with 2,5-diamino 1,4-benzene dithiol dihydrochloride (DABDT.2 HCl) affords the polymer poly {[benzo (1,2-d: 4,5-d’) bisthiazole-2, 6 diyl]-1,3 phenylene} and poly {[benzo (1,2-d: 4,5-d’) bisthiazole-2, 6 diyl]-1,3(5-hydroxy phenylene)}. Both the polymers were soluble in methanesulphonic acid and chlorosulphonic acid. The polybenzobisthiazoles do not show any glass transition temperature (Tg) by DSC analysis. The polybenzobisthiazoles were stable up to 400oC in a nitrogen environment, according to thermo gravimetric measurements. Elemental analysis and spectroscopic comparison of the polymers with the appropriate model compounds were used to confirm the polymer structures. The polymers' inherent viscosity reached 4.2 dL/g (methanesulphonic acid, 30oC).
期刊介绍：
RASĀYAN Journal of Chemistry [RJC] signifies a confluence of diverse streams of chemistry to stir up the cerebral powers of its contributors and readers. By introducing the journal by this name, we humbly intent to provide an open platform to all researchers, academicians and readers to showcase their ideas and research findings among the people of their own fraternity and to share their vast repository of knowledge and information. The journal seeks to embody the spirit of enquiry and innovation to augment the richness of existing chemistry literature and theories. We also aim towards making this journal an unparalleled reservoir of information and in process aspire to inculcate and expand the research aptitude.
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