SYNTHESIS AND CHARACTERIZATION OF BENZOXAZINE: URETHANE COPOLYMER FROM VANILLIN WITH ADAMANTANE SIDE CHAIN AND ITS ANTICORROSIVE COATING ON MILD STEEL

IF 0.5 Q4 EDUCATION & EDUCATIONAL RESEARCH Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI:10.31788/rjc.2023.1628362
K. Jayanthi, M. Sivaraju
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Abstract

Corrosion is a significant issue with metallic materials, notably in steel due to its extensive use in a variety of industries. Benzoxazine polymers have been used to produce anti-corrosive compounds that have a remarkable ability to limit corrosion. In the same ink line, we have explored a new approach with a very hydrophobic benzoxazine monomer which is co-polymerized with urethane, and its characterization was studied with IR, UV, and NMR techniques. The corrosion resistance of the same is investigated using Tafel polarization and EIS experiment methodologies. The DFT and MEP studies explain the reactivity towards the anti-corrosive properties of the monomer.
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含金刚烷侧链香兰素-氨基甲酸乙酯共聚物的合成与表征及其在低碳钢上的防腐涂层
腐蚀是金属材料的一个重要问题,特别是钢铁,因为它在各种工业中广泛使用。苯并恶嗪聚合物已被用于生产具有显著的抗腐蚀能力的防腐化合物。在同一墨线上,我们探索了一种与聚氨酯共聚的疏水性极强的苯并恶嗪单体的新方法,并用红外、紫外和核磁共振技术对其进行了表征。采用Tafel极化和EIS实验方法对其耐腐蚀性能进行了研究。DFT和MEP研究解释了反应性对单体防腐性能的影响。
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来源期刊
Rasayan Journal of Chemistry
Rasayan Journal of Chemistry Energy-Energy (all)
CiteScore
1.90
自引率
0.00%
发文量
196
期刊介绍: RASĀYAN Journal of Chemistry [RJC] signifies a confluence of diverse streams of chemistry to stir up the cerebral powers of its contributors and readers. By introducing the journal by this name, we humbly intent to provide an open platform to all researchers, academicians and readers to showcase their ideas and research findings among the people of their own fraternity and to share their vast repository of knowledge and information. The journal seeks to embody the spirit of enquiry and innovation to augment the richness of existing chemistry literature and theories. We also aim towards making this journal an unparalleled reservoir of information and in process aspire to inculcate and expand the research aptitude.
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