Investigation of Physical Properties of Fe(III) Containing Metal-Organic Polymers

A. Y. Ershova, Minggong Sha
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引用次数: 2

Abstract

In this work, we studied the properties of a specially synthesized organometallic coordination polymer - a porous coordination polymer with biocompatible structural elements based on oxoclusters of iron muconate (III). The samples were investigated by scanning electron microscopy, thermogravimetric analysis combined with differential scanning calorimetry, and the study of low-temperature nitrogen adsorption of a sample obtained by a modified solvothermal technique. It is shown that most of the pores of the sample have an average radius of 18,8 Å ~ 1,88 nm. Also, as a result of the study, it is necessary to conclude that the synthesized material has a developed surface area - it is 512,1 m2/g and the pore volume is ~ 0,48 cm3/g. It should be concluded that such materials are promising as components for a new generation of various kinds of functional materials with improved or unique characteristics. It is obvious that further research in this area is important from both fundamental and applied points of view.
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含铁(III)金属有机聚合物的物理性质研究
在这项工作中,我们研究了一种特殊合成的有机金属配位聚合物-一种基于铁酸盐氧簇(III)的具有生物相容性结构元素的多孔配位聚合物。通过扫描电子显微镜,热重分析结合差示扫描量热法研究了样品的性质,并研究了通过改进的溶剂热技术获得的样品的低温氮吸附。结果表明,样品中大部分孔隙的平均半径为18.8 Å ~ 1.88 nm。同时,根据研究结果,有必要得出结论,合成材料具有发达的表面积-其为512,1 m2/g,孔隙体积为~ 0,48 cm3/g。因此,这些材料有望成为具有改进或独特特性的新一代各种功能材料的组成部分。显然,从基础和应用的角度来看,这一领域的进一步研究都很重要。
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来源期刊
International Journal of Mechanics
International Journal of Mechanics Engineering-Computational Mechanics
CiteScore
1.60
自引率
0.00%
发文量
17
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