Effect of Particle Addition on Ultrasonic Degradation Reaction Rate

D. Kobayashi, Kaho Shimakage, Chiemi Honma, H. Matsumoto, K. Otake, A. Shono
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引用次数: 3

Abstract

The ultrasonic degradation of methylene blue at a frequency of 490 kHz was carried out in the absence and presence of TiO2 or Al2O3 particle, and the effects of amounts of particle on the enhancement of degradation rate constant estimated by assuming first-order-kinetics were investigated. The degradation reaction was enhanced by particle addition, and the apparent degradation rate constant is proportional to the increase in amount of particle. In addition, the constant of proportionality is not influenced by degraded material and ultrasonic frequency. However, particle type influences the constant of proportionality, and the value of TiO2 particle is about 6 times as large as that of Al2O3 particle.
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颗粒添加对超声降解反应速率的影响
在490 kHz频率下对亚甲基蓝进行了TiO2和Al2O3颗粒存在和不存在的超声降解实验,考察了TiO2和Al2O3颗粒数量对一阶动力学估计的亚甲基蓝降解速率常数的影响。颗粒的加入增强了降解反应,且表观降解速率常数与颗粒量的增加成正比。此外,比例常数不受降解材料和超声频率的影响。而颗粒类型对比例常数有影响,TiO2颗粒的比例常数约为Al2O3颗粒的6倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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