Single and Sequential Extraction of Copper by Different Extractants from Different Peat Soil Samples of Bangladesh

Ishrat Jahan Sanchary, Tania Akter
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Abstract

A comprehensive in vitro study on single and sequential extraction methods for Cu exraction by different extractants of distinct chemical nature from some peat soils of Bangladesh was conducted to assess the pattern of metal-extractability in drying and wetting sequences. Samples were collected from peat basins of two different districts of Bangladesh (Gopalgonj and Bagerhat) and an incubation study was designed and conducted in which soils were incubated to three alternate drying and wetting cycles for 21 days. Single and sequentially extracted Cu ions in all three cycles and by all three selective extractants were compared. Maximum amount of Cu was extracted in drying days and 1M HCl extracted the largest proportion of Cu from all the soils in each incubation time. Conversely, 1M NH4Cl was the least effective extractant for extracting Cu by both single and sequential process in either day of incubation. Considerable amount of Cu was extracted by 0.005 M DTPA in dry periods. In general, single extraction was found to be more effective in extracting Cu in the alternate drying and wetting cycles from the peat soil samples except for 1M HCl in initial drying days.
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不同萃取剂从孟加拉国不同泥炭土样品中单次和顺序萃取铜
本文对不同化学性质的萃取剂从孟加拉国泥炭土中提取铜的单次和顺序萃取方法进行了全面的体外研究,以评估干燥和湿润顺序中金属可萃取性的模式。从孟加拉国两个不同地区(Gopalgonj和Bagerhat)的泥炭盆地收集了样本,并设计和开展了一项培养研究,在该研究中,将土壤培养为三个干湿交替循环,持续21天。比较了三种萃取剂对铜离子的单次萃取和顺序萃取效果。在各培养时间内,各土壤中铜的提取量以1M HCl的提取量最大。相反,在孵育的任何一天,1M NH4Cl在单次和连续过程中都是最不有效的萃取剂。在干燥期,0.005 M DTPA萃取了相当数量的铜。总的来说,在干湿交替循环中,除了在干燥初期使用1M HCl外,单次提取对泥炭土样品中的铜更有效。
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