{"title":"Functionalization of fullerene with 4-benzo-9-crown-3 ether","authors":"K. Maryam, Mouji Hamid, Eskandari Hossein","doi":"10.56042/ijct.v30i1.64953","DOIUrl":null,"url":null,"abstract":":هلاقم هصلاخ Functionalization ofFullerene by the covalent addition of ۴-benzo-۹-crown-۳ether diazonium salt has beendescribed. The covalent grafting ofcrown etherhas led to a considerable increase in the solubility ofFullerene in both organicand aquatic solvents such as ethanol, dimethylsulfoxide, dimethylformamideand water. The highest solubilitywas attained in Dichloromethane, Acetone andEthanol. The covalently bonded ۴-benzo-۹-crown-۳ ether allowed the hosting ofLi+. The covalentgrafting of crown ether [۴-(benzo-۹-crown-۳)] to Fullerenewasidentified and confirmed by infrared spectroscopy, UV/Vis andthermogravimetric analysismethods.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indian Journal of Chemical Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.56042/ijct.v30i1.64953","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
:هلاقم هصلاخ Functionalization ofFullerene by the covalent addition of ۴-benzo-۹-crown-۳ether diazonium salt has beendescribed. The covalent grafting ofcrown etherhas led to a considerable increase in the solubility ofFullerene in both organicand aquatic solvents such as ethanol, dimethylsulfoxide, dimethylformamideand water. The highest solubilitywas attained in Dichloromethane, Acetone andEthanol. The covalently bonded ۴-benzo-۹-crown-۳ ether allowed the hosting ofLi+. The covalentgrafting of crown ether [۴-(benzo-۹-crown-۳)] to Fullerenewasidentified and confirmed by infrared spectroscopy, UV/Vis andthermogravimetric analysismethods.
期刊介绍:
Indian Journal of Chemical Technology has established itself as the leading journal in the exciting field of chemical engineering and technology. It is intended for rapid communication of knowledge and experience to engineers and scientists working in the area of research development or practical application of chemical technology. This bimonthly journal includes novel and original research findings as well as reviews in the areas related to – Chemical Engineering, Catalysis, Leather Processing, Polymerization, Membrane Separation, Pharmaceuticals and Drugs, Agrochemicals, Reaction Engineering, Biochemical Engineering, Petroleum Technology, Corrosion & Metallurgy and Applied Chemistry.