Evolution of the structure of MSnO3 (M = Ba, Sr) perovskites during hydrothermal synthesis and their photocatalytic activity

Abstract

The synthesis of barium and strontium stannates in the process of decomposition of hydrothermally obtained precursors has been investigated. It was found that endothermic weight loss during the synthesis of barium stannate occurs in two stages, whereas during the synthesis of strontium stannate it occurs in one stage. From the summary of the results of thermogravimetric analysis, X-ray diffraction, and Mössbauer spectroscopy, the composition and local structure of X-ray amorphous phases are proposed. It is shown that the improvement of the crystal structure of the perovskite phases of MSnO₃ (M = Ba, Sr) and the symmetry of the local environment of ¹¹⁹Sn continues up to high temperatures (1250–1500 °C) and is associated with the elimination of defects in the anion sublattice. The photocatalytic activity of hydrothermal phases MSn(OH)₆ and their thermolysis products has been studied and was found not to be directly related to the specific surface area of the photocatalysts. The degradation of rhodamine B (RhB) occurs during the “dark” stages of catalysis due to the interaction of the dye with reactive oxygen species (mainly singlet oxygen). At the first stage, the decomposition of the RhB photochromic system is observed, whereas at the final stage of bleaching the dye is deethylated.