{"title":"Structure and magnetic properties of the ThMn2-type compounds RFe12−xRex (R Ce-Nd, Sm, Gd−Tm, Lu, Y, Th, U)","authors":"M Gueramian, K Yvon, F Hulliger","doi":"10.1016/0022-5088(91)90018-Y","DOIUrl":null,"url":null,"abstract":"<div><p>The compounds RFe<sub>12−x</sub>Re<sub>x</sub> (<em>R</em> <em>Ce</em>, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu, Y, Th, U) were synthesized at the nominal composition <em>x</em> = 2 by arc melting from the elements followed by annealing. The poly crystalline samples were examined by X-ray powder diffraction and magnetization measurements. They all crystallize with a partially substituted tetragonal ThMn<sub>12</sub>-type structure and are magnetically ordered with Curie temperatures in the range <em>T</em><sub><em>c</em></sub> = 340(<em>U</em>)-475(<em>Sm</em>) K and magnetic moments at 4.2 K in the range 8.0(Dy)–21.4(Nd) <em>μ</em><sub><em>B</em></sub> per formula unit. Atomic coordinates are given for two members with refined compositions, PrFe<sub>10.5</sub>Re<sub>1.5</sub> and GdFe<sub>10.6</sub>Re<sub>1.4</sub>.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 321-330"},"PeriodicalIF":0.0000,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90018-Y","citationCount":"10","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Less Common Metals","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/002250889190018Y","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
Abstract
The compounds RFe12−xRex (R Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu, Y, Th, U) were synthesized at the nominal composition x = 2 by arc melting from the elements followed by annealing. The poly crystalline samples were examined by X-ray powder diffraction and magnetization measurements. They all crystallize with a partially substituted tetragonal ThMn12-type structure and are magnetically ordered with Curie temperatures in the range Tc = 340(U)-475(Sm) K and magnetic moments at 4.2 K in the range 8.0(Dy)–21.4(Nd) μB per formula unit. Atomic coordinates are given for two members with refined compositions, PrFe10.5Re1.5 and GdFe10.6Re1.4.
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