Effect of sintering temperature and time on corrosion characteristics of aluminum matrix composites

IF 2.9 Q2 ELECTROCHEMISTRY Journal of Electrochemical Science and Engineering Pub Date : 2023-07-26 DOI:10.5599/jese.1891
Sahib M. Mahdi, L. Ghalib
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Abstract

Aluminum matrix composites outperform traditional alloys in terms of mechanical properties and corrosion resistance. Silicon carbide is the main reinforcing material in aluminum-based composites that have developed rapidly in recent years. In this investigation, aluminum-silicon carbide composites were prepared through powder metallurgy with 10 and 20 wt.% of silicon carbide reinforcement. The influence of the SiC content, sintering temperature, and sintering time on the corrosion behavior of prepared Al-SiC composites in 0.5 M hydrochloride acid solution was assessed. The surface microstructure was characterized by scanning electron microscopy with energy dispersive analysis and X-rays. The experimental results demonstrated how the sintering parameters can affect the corrosion characteristics of sintered samples. The electrochemical analysis curves showed that when increasing the sintering temperature and sintering time, there is a possibility of self-repair of damaged passive film on the surface while further reinforcing of the composite with silicon carbide prevents penetration of chloride ions. The SEM images and EDS analysis of composite surfaces after being corroded in 0.5 M HCl revealed that increasing the sintering temperature and prolonging the sintering time reduce the pitting corrosion of composites.  
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烧结温度和时间对铝基复合材料腐蚀特性的影响
铝基复合材料在机械性能和耐腐蚀性方面优于传统合金。碳化硅是近年来发展迅速的铝基复合材料中的主要增强材料。采用粉末冶金法制备了碳化硅增强量分别为10%和20%的铝硅复合材料。考察了SiC含量、烧结温度和烧结时间对制备的Al-SiC复合材料在0.5 M盐酸溶液中的腐蚀行为的影响。利用扫描电子显微镜、能谱分析和x射线对其表面微观结构进行了表征。实验结果证明了烧结参数对烧结试样腐蚀特性的影响。电化学分析曲线表明,提高烧结温度和烧结时间,表面受损的钝化膜有自我修复的可能,而进一步用碳化硅增强复合材料可以防止氯离子的渗透。复合材料在0.5 M HCl中腐蚀后的SEM图像和EDS分析表明,提高烧结温度和延长烧结时间可以降低复合材料的点蚀。
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来源期刊
CiteScore
3.60
自引率
27.30%
发文量
90
审稿时长
6 weeks
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