Thermal and optical properties of flake-like copper oxide nanostructure

A. Das, A. Meikap
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Abstract

The flake-like copper oxide (CuO) nanoparticles have been synthesized by calcination method. The XRD pattern and EDX elemental mapping confirms the formation of CuO nanostructure with average crystallite size 4.8 nm. The weight loss of the synthesized material at 800 °C is only 8%. A broad UV-absorption peak arises at 326 nm. A blue shift is observed for the CuO nano-flake. The direct optical band gap value is 2.7 eV and 4.7 eV. A sharp intense peak in the PL spectrum display at 334 nm.The flake-like copper oxide (CuO) nanoparticles have been synthesized by calcination method. The XRD pattern and EDX elemental mapping confirms the formation of CuO nanostructure with average crystallite size 4.8 nm. The weight loss of the synthesized material at 800 °C is only 8%. A broad UV-absorption peak arises at 326 nm. A blue shift is observed for the CuO nano-flake. The direct optical band gap value is 2.7 eV and 4.7 eV. A sharp intense peak in the PL spectrum display at 334 nm.
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片状氧化铜纳米结构的热光学性质
采用煅烧法制备了片状氧化铜纳米颗粒。XRD图和EDX元素图证实形成了平均晶粒尺寸为4.8 nm的CuO纳米结构。合成材料在800℃时失重率仅为8%。在326 nm处出现宽紫外吸收峰。在CuO纳米薄片上观察到蓝移现象。直接光学带隙值分别为2.7 eV和4.7 eV。在334 nm处有一个明显的强峰。采用煅烧法制备了片状氧化铜纳米颗粒。XRD图和EDX元素图证实形成了平均晶粒尺寸为4.8 nm的CuO纳米结构。合成材料在800℃时失重率仅为8%。在326 nm处出现宽紫外吸收峰。在CuO纳米薄片上观察到蓝移现象。直接光学带隙值分别为2.7 eV和4.7 eV。在334 nm处有一个明显的强峰。
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