{"title":"Highly efficient and regioselective cyclization catalyzed by TS-1","authors":"A. Bhaumik, T. Tatsumi","doi":"10.1021/bk-2000-0738.ch005","DOIUrl":null,"url":null,"abstract":"In this paper we report a highly efficient regioselective cyclization of such olefinic alcohols over TS-1, under mild reaction conditions using dilute hydrogen peroxide as oxidant. Similar types of oxidative cyclization (bifunctional behavior, epoxidation followed by acid catalyzed cyclization) was observed in the oxidation of linalool over Al-Ti-Beta and Al-Ti-MCM-41 where the acidity at the Al sites was responsible for the cyclization.","PeriodicalId":20402,"journal":{"name":"Preprints-American Chemical Society Division of Petroleum Chemistry","volume":"195 1","pages":"231-233"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preprints-American Chemical Society Division of Petroleum Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1021/bk-2000-0738.ch005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
In this paper we report a highly efficient regioselective cyclization of such olefinic alcohols over TS-1, under mild reaction conditions using dilute hydrogen peroxide as oxidant. Similar types of oxidative cyclization (bifunctional behavior, epoxidation followed by acid catalyzed cyclization) was observed in the oxidation of linalool over Al-Ti-Beta and Al-Ti-MCM-41 where the acidity at the Al sites was responsible for the cyclization.
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