High-temperature vibrational spectroscopy of molten electrolytes

IF 5.4 2区化学 Q1 INSTRUMENTS & INSTRUMENTATION Applied Spectroscopy Reviews Pub Date : 2022-03-08 DOI:10.1080/05704928.2022.2048305

M. M. Gafurov, K. Rabadanov

{"title":"High-temperature vibrational spectroscopy of molten electrolytes","authors":"M. M. Gafurov, K. Rabadanov","doi":"10.1080/05704928.2022.2048305","DOIUrl":null,"url":null,"abstract":"Abstract Spectroscopic studies of molten electrolytes have been carried out for more than 50 years. The information available in the literature on the problems arising in high-temperature spectroscopic measurements of molten electrolytes, as well as methods and technical solutions to overcome them, and the design of optical heating cells used for these purposes is fragmentary. The purpose of this review is to summarize the information available in the literature on techniques and methods for high-temperature spectroscopic measurements of molten electrolytes. A description of various techniques used in spectroscopic studies of molten electrolytes, including IR transmission spectroscopy, reflection and emission spectroscopy, reflection-adsorption spectroscopy, spectroelectrochemical Raman and IR spectroscopy is presented. A description of the design of the corresponding optical heating cells is given, as well as examples of spectra obtained using them. The review is useful for researchers studying electrolyte melts and specialists developing medium-temperature chemical current sources based on them. GRAPHICAL ABSTRACT","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"86 1","pages":"489 - 508"},"PeriodicalIF":5.4000,"publicationDate":"2022-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Spectroscopy Reviews","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/05704928.2022.2048305","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"INSTRUMENTS & INSTRUMENTATION","Score":null,"Total":0}

引用次数: 3

Abstract

Abstract Spectroscopic studies of molten electrolytes have been carried out for more than 50 years. The information available in the literature on the problems arising in high-temperature spectroscopic measurements of molten electrolytes, as well as methods and technical solutions to overcome them, and the design of optical heating cells used for these purposes is fragmentary. The purpose of this review is to summarize the information available in the literature on techniques and methods for high-temperature spectroscopic measurements of molten electrolytes. A description of various techniques used in spectroscopic studies of molten electrolytes, including IR transmission spectroscopy, reflection and emission spectroscopy, reflection-adsorption spectroscopy, spectroelectrochemical Raman and IR spectroscopy is presented. A description of the design of the corresponding optical heating cells is given, as well as examples of spectra obtained using them. The review is useful for researchers studying electrolyte melts and specialists developing medium-temperature chemical current sources based on them. GRAPHICAL ABSTRACT

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

熔融电解质的高温振动光谱

熔融电解质的光谱研究已经进行了50多年。关于熔融电解质高温光谱测量中出现的问题，以及克服这些问题的方法和技术解决方案，以及用于这些目的的光学加热电池的设计，文献中提供的信息是零碎的。本文综述了熔融电解质高温光谱测量技术和方法的文献资料。介绍了用于熔融电解质光谱研究的各种技术，包括红外透射光谱、反射和发射光谱、反射-吸附光谱、光谱电化学拉曼光谱和红外光谱。给出了相应的光加热电池的设计，以及使用它们获得光谱的例子。该综述对研究电解质熔体的研究人员和基于它们开发中温化学电流源的专家有一定的参考价值。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Applied Spectroscopy Reviews 工程技术-光谱学

CiteScore

13.80

自引率

1.60%

发文量

审稿时长

1 months

期刊介绍： Applied Spectroscopy Reviews provides the latest information on the principles, methods, and applications of all the diverse branches of spectroscopy, from X-ray, infrared, Raman, atomic absorption, and ESR to microwave, mass, NQR, NMR, and ICP. This international, single-source journal presents discussions that relate physical concepts to chemical applications for chemists, physicists, and other scientists using spectroscopic techniques.