Pub Date : 2025-10-14DOI: 10.1080/05704928.2025.2571435
Hongxin Wang, Yoshitaka Yoda, Jessie Wang, Stephen P Cramer, Hideaki Ogata
Nuclear resonant vibrational spectroscopy (NRVS) is a synchrotron based modern vibrational spectroscopy starting in mid 1990s. This review article focuses on a series of practical issues presented in NRVS for measuring biological samples, which have dilute concentrations, complicated molecular structures and unstable/meta stable enzymatic/chemical states. The main sections (Sec. 2 to Sec. 6) discuss the special problems facing these circumstances and the solutions to the problems. The example tasks include obtaining extra incident beam flux, calibrating energies for sectional scans, reducing real sample temperatures, reducing background counts while keep NRVS signal levels, manipulating and monitoring samples, as well as judging the best simulations. All these are critical for successful measurement and understanding of a bio-NRVS spectrum, especially of the one with extremely weak feature(s), e.g. the iron-hydride(s) inside various hydrogenases. The last section (Sec. 7) provides the readers with information about the latest researches and enlightenments about the future researches. In addition, Sec. 1 provides a simple but still explanatory introduction for NRVS beginners. This article will especially be useful as an overall guide for NRVS users, beamline scientists, and biochemists who make biological samples to work together on the entangled multiple discipline problems facing bio-NRVS. It will also provide general enlightenment for other spectroscopists to resolve entangled issues in their measurements and researches, especially in vibrational spectroscopies and synchrotron related spectroscopies.
{"title":"Practical issues in nuclear resonant vibrational spectroscopy for measuring biological samples: special problems, solutions and some perspectives.","authors":"Hongxin Wang, Yoshitaka Yoda, Jessie Wang, Stephen P Cramer, Hideaki Ogata","doi":"10.1080/05704928.2025.2571435","DOIUrl":"10.1080/05704928.2025.2571435","url":null,"abstract":"<p><p>Nuclear resonant vibrational spectroscopy (NRVS) is a synchrotron based modern vibrational spectroscopy starting in mid 1990s. This review article focuses on a series of practical issues presented in NRVS for measuring biological samples, which have dilute concentrations, complicated molecular structures and unstable/meta stable enzymatic/chemical states. The main sections (Sec. 2 to Sec. 6) discuss the special problems facing these circumstances and the solutions to the problems. The example tasks include obtaining extra incident beam flux, calibrating energies for sectional scans, reducing real sample temperatures, reducing background counts while keep NRVS signal levels, manipulating and monitoring samples, as well as judging the best simulations. All these are critical for successful measurement and understanding of a bio-NRVS spectrum, especially of the one with extremely weak feature(s), e.g. the iron-hydride(s) inside various hydrogenases. The last section (Sec. 7) provides the readers with information about the latest researches and enlightenments about the future researches. In addition, Sec. 1 provides a simple but still explanatory introduction for NRVS beginners. This article will especially be useful as an overall guide for NRVS users, beamline scientists, and biochemists who make biological samples to work together on the entangled multiple discipline problems facing bio-NRVS. It will also provide general enlightenment for other spectroscopists to resolve entangled issues in their measurements and researches, especially in vibrational spectroscopies and synchrotron related spectroscopies.</p>","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":" ","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12711139/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145780181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.1080/05704928.2024.2397594
Shuqi Yu, Wen-Lin Feng, Wenqiang Lu, Maxim V. Trigub
The on-chip gas sensors possess advantages, such as miniaturization, portability, low power, and no need for optical path calibration. These benefits enhance the applications of these sensors, such...
{"title":"Recent progress in infrared absorption spectroscopy for on-chip waveguide gas sensing","authors":"Shuqi Yu, Wen-Lin Feng, Wenqiang Lu, Maxim V. Trigub","doi":"10.1080/05704928.2024.2397594","DOIUrl":"https://doi.org/10.1080/05704928.2024.2397594","url":null,"abstract":"The on-chip gas sensors possess advantages, such as miniaturization, portability, low power, and no need for optical path calibration. These benefits enhance the applications of these sensors, such...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"6 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142217940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.1080/05704928.2024.2398196
Minchao Cui, Shilei Xiong, Nan Yang, Yuanbin Wang, Zhenzhen Wang, Ming Luo, Changfeng Yao, Yoshihiro Deguchi
As a crucial detection technology in the era of digital transformation, laser induced breakdown spectroscopy (LIBS) has been widely used in industrial measurement and monitoring. In recent years, t...
{"title":"Applications of laser-induced breakdown spectroscopy in industrial measurement and monitoring: Multi-technology combination","authors":"Minchao Cui, Shilei Xiong, Nan Yang, Yuanbin Wang, Zhenzhen Wang, Ming Luo, Changfeng Yao, Yoshihiro Deguchi","doi":"10.1080/05704928.2024.2398196","DOIUrl":"https://doi.org/10.1080/05704928.2024.2398196","url":null,"abstract":"As a crucial detection technology in the era of digital transformation, laser induced breakdown spectroscopy (LIBS) has been widely used in industrial measurement and monitoring. In recent years, t...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"48 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-19DOI: 10.1080/05704928.2024.2390962
Catarina F. Araújo, Dinis O. Abranches, João A. P. Coutinho, Pedro D. Vaz, Paulo Ribeiro-Claro, Mariela M. Nolasco
This review highlights the variety of ways in which vibrational spectroscopy can be of use in understanding why deep eutectic solvents (DESs) behave the way they do. Throughout six themed sub-secti...
{"title":"Good vibrations: understanding deep eutectic solvents through the lens of vibrational spectroscopy","authors":"Catarina F. Araújo, Dinis O. Abranches, João A. P. Coutinho, Pedro D. Vaz, Paulo Ribeiro-Claro, Mariela M. Nolasco","doi":"10.1080/05704928.2024.2390962","DOIUrl":"https://doi.org/10.1080/05704928.2024.2390962","url":null,"abstract":"This review highlights the variety of ways in which vibrational spectroscopy can be of use in understanding why deep eutectic solvents (DESs) behave the way they do. Throughout six themed sub-secti...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"7 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142217943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-19DOI: 10.1080/05704928.2024.2388521
Lijun Feng, Jiangle Zhang, Jiajia Yuan, Yan Hu, Jin Liu, Xinfeng Zhang
Pharmaceuticals and personal care products (PPCPs), a class of emerging pollutants, can accumulate in the environment and cause endocrine disruption, damage to the reproductive system, even cancer....
{"title":"Gold nanoparticles-based colorimetric determination of pharmaceuticals and personal care products: from sensing methodology to application","authors":"Lijun Feng, Jiangle Zhang, Jiajia Yuan, Yan Hu, Jin Liu, Xinfeng Zhang","doi":"10.1080/05704928.2024.2388521","DOIUrl":"https://doi.org/10.1080/05704928.2024.2388521","url":null,"abstract":"Pharmaceuticals and personal care products (PPCPs), a class of emerging pollutants, can accumulate in the environment and cause endocrine disruption, damage to the reproductive system, even cancer....","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"4 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142217941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1080/05704928.2024.2369570
Xueying Li, Huimin Qiu, Pingping Fan
The estimation of soil organic carbon based on visible near-infrared spectroscopy (VNIR) and hyperspectral image (HSI) has many advantages. However, the estimation accuracy has been a challenge tha...
{"title":"A review of spectral feature extraction and multi-feature fusion methods in predicting soil organic carbon","authors":"Xueying Li, Huimin Qiu, Pingping Fan","doi":"10.1080/05704928.2024.2369570","DOIUrl":"https://doi.org/10.1080/05704928.2024.2369570","url":null,"abstract":"The estimation of soil organic carbon based on visible near-infrared spectroscopy (VNIR) and hyperspectral image (HSI) has many advantages. However, the estimation accuracy has been a challenge tha...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"18 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1080/05704928.2024.2367450
Yurim Han, Paolo Matteini, Byungil Hwang
Surface-enhanced Raman spectroscopy (SERS) has gained increasing attention for sensing chemicals and molecules at low concentrations. Localized surface plasmons (LSPs) that occur on metal nanostruc...
{"title":"Fabrication method of colloidal dispersions and substrates for detection of pesticide, veterinary drug, and biomolecule using surfaced-enhanced Raman spectroscopy: a review","authors":"Yurim Han, Paolo Matteini, Byungil Hwang","doi":"10.1080/05704928.2024.2367450","DOIUrl":"https://doi.org/10.1080/05704928.2024.2367450","url":null,"abstract":"Surface-enhanced Raman spectroscopy (SERS) has gained increasing attention for sensing chemicals and molecules at low concentrations. Localized surface plasmons (LSPs) that occur on metal nanostruc...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"215 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-03DOI: 10.1080/05704928.2024.2359933
Xinyu Zhao, HongChao Qi, Yufu Xu, Chenxi Li, Min Guo, Ke Chen
Fiber-optic photoacoustic (PA) sensing has important applications in trace gas detection. The fiber-optic Fabry-Perot acoustic sensor implemented applying a cantilever is a novel and highly sensiti...
{"title":"Fiber-optic photoacoustic gas sensing: a review","authors":"Xinyu Zhao, HongChao Qi, Yufu Xu, Chenxi Li, Min Guo, Ke Chen","doi":"10.1080/05704928.2024.2359933","DOIUrl":"https://doi.org/10.1080/05704928.2024.2359933","url":null,"abstract":"Fiber-optic photoacoustic (PA) sensing has important applications in trace gas detection. The fiber-optic Fabry-Perot acoustic sensor implemented applying a cantilever is a novel and highly sensiti...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"41 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-28DOI: 10.1080/05704928.2024.2355193
Nargiza Eshbekova, A. Sowndarya, T. Daniel Thangadurai, Yong-Ill Lee
Raman spectroscopy (RS) is a nondestructive analytical method extensively utilized in the field of biomedical, and pharmaceutical applications due to their high sensitivity, noninvasive, and select...
{"title":"Recent advancements in Raman instrumentation and capabilities for pharmaceutical and biomedical applications","authors":"Nargiza Eshbekova, A. Sowndarya, T. Daniel Thangadurai, Yong-Ill Lee","doi":"10.1080/05704928.2024.2355193","DOIUrl":"https://doi.org/10.1080/05704928.2024.2355193","url":null,"abstract":"Raman spectroscopy (RS) is a nondestructive analytical method extensively utilized in the field of biomedical, and pharmaceutical applications due to their high sensitivity, noninvasive, and select...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"19 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141168758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-12DOI: 10.1080/05704928.2024.2335380
Xu Wu, Jing Wu, Jiawei Li, Yan Peng, Yiming Zhu
The α-dicarbonyl compounds are glycolysis metabolites with high reactivity that can cause damage to nucleic acids, proteins, and other macromolecules, leading to various chronic diseases. The rapid...
{"title":"Advances in detecting α-dicarbonyl compounds: Insights from spectroscopic techniques","authors":"Xu Wu, Jing Wu, Jiawei Li, Yan Peng, Yiming Zhu","doi":"10.1080/05704928.2024.2335380","DOIUrl":"https://doi.org/10.1080/05704928.2024.2335380","url":null,"abstract":"The α-dicarbonyl compounds are glycolysis metabolites with high reactivity that can cause damage to nucleic acids, proteins, and other macromolecules, leading to various chronic diseases. The rapid...","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"38 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140560915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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