Fabrication and Electrochemical Performance of LiFePO4/C as Cathode Material for Lithium Ion Battery

L. Hasanah, A. Purwanto, Inayati, Eva Dyah Pambayun, Aditiya Septaningtyas
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引用次数: 2

Abstract

The research for cheap and abundant LiFeP04/C as cathode material of lithium-ion battery became a trending topic in this century. LiFePO4/C particles were commonly used due to its environmental acceptability. This research was aimed to compare methods for preparing LiFePO4/C particles using solid state and flame assisted spray pyrolysis method. The variable of studied at variation molar ratio $\mathrm{Li: Fe: P}$ of $1: 1:1\ 1.1:1:1:\ 1.2:1:1$; and $1.3: 1: 1$. The crystalline structure was characterized by X-Ray Diffraction (XRD). The morphology was characterized using SEM test. The electrochemical performance was characterized using battery analyzer. Based on data, still exhibits some impurities. The particle still in micron-sized. The highest initial discharge capacity at molar ratio $\mathrm{Li: Fe: P}$ of $1.1:1:1$ is 46.1 mAh g−1 at 1/20 C.
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锂离子电池正极材料LiFePO4/C的制备及其电化学性能
廉价、丰富的LiFeP04/C作为锂离子电池正极材料的研究成为本世纪的热门话题。LiFePO4/C颗粒由于其环境可接受性而被广泛使用。本研究旨在比较固相法和火焰辅助喷雾热解法制备LiFePO4/C颗粒的方法。研究了摩尔比变化时的变量$\ mathm {Li: Fe: P}$ of $ 1:1\ 1.1:1:1:\ 1.2:1:1$;1.3美元:1:1美元。用x射线衍射(XRD)对晶体结构进行了表征。采用扫描电镜对其形貌进行表征。利用电池分析仪对其电化学性能进行了表征。根据数据,仍然显示出一些杂质。颗粒仍在微米级。当摩尔比$\ mathm {Li: Fe: P}$为$1.1:1:1$时,在1/20℃下的最高初始放电容量为46.1 mAh g−1。
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