I–V performances of aligned ZnO nanorods/Mg0.3Zn0.7O thin film heterojunction for MESFET applications

S. Muhamad, M. Z. Sahdan, M. H. Mamat, M. Rusop
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Abstract

Zinc oxide (ZnO) is a promising candidates for electronics devices applications due to its unique properties that being extensively explored nowadays. Having a large bandgap of 3.4 eV at room temperature and large exciton binding energy of 60 meV [1] has made ZnO to become transparent to visible light. MgZnO also transparent to visible light where the bandgap can be tailored to reach almost 4.6 eV [2]. By introducing these two transparent materials in MESFET applications, such transistor could be particularly useful in display technologies as the transistor will no longer block the light. Mg0.3Zn0.7O with the resistance of 106 Ω/cm [3], can acts as a semi-insulating material in MESFET structure, was deposited on quartz substrate before being immersed in ZnO solution for 4.5 hours. The ZnO solution of 0.05M was prepared one day earlier, was stirred and heat, before being left at room temperature to get better solubility. This chemical bath deposition technique was believed to be very easy, low cost technique, yet can produced a very uniform, aligned ZnO nanorods. Field emission scanning electron microscope (FESEM) depicts that an aligned ZnO nanorods were successfully grown as in Fig. 1 on Mg0.3Zn0.7O that in the other way has acted as a catalyst for the better growth of aligned ZnO. The diameter of the nanorod has found out to be in the average of 75 nm while the thickness is around 1.6 µm. X-ray diffraction spectra has recorded that this aligned ZnO shows very intense (002) peak, which was between 15° and 60°, indicating a high degree of crystallinity. Keithley measurement system has been employed to study the IV response of this heterojunction of ZnO/Mg0.3Zn0.7O. It is well understood that different metal used as a contact will resulted in a different behavior of IV responses. Due to that, 4 different metals has been used to study the IV responses. For the metallization purposed, electron beam evaporator has been employed to deposit aluminum, gold, platinum and nickel as a metal contact. It shows that these 4 selected metals gave different behavior of IV responses due to different work function of each metal. To study the performance of aligned ZnO/Mg0.3Zn0.7O heterostructures, the IV response of thin film ZnO, thin film ZnO/Mg0.3Zn0.7O, and thin film Mg0.3Zn0.7O has been taken as a reference. It obviously revealed that aligned ZnO/Mg0.3Zn0.7O heterostructures gave better performance of IV responses compared to others which will be discussed further in this paper. It is suggested that this heterostructures can be used in MESFET applications due to its simplicity in fabrication and the IV performance that suitable for the use of transparent transistor in display technologies.
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用于MESFET的排列ZnO纳米棒/Mg0.3Zn0.7O薄膜异质结的I-V性能
氧化锌(ZnO)由于其独特的性能,在电子器件中应用前景广阔。ZnO在室温下具有3.4 eV的大带隙和60 meV[1]的大激子结合能,使其对可见光透明。MgZnO对可见光也是透明的,其带隙可以达到近4.6 eV[2]。通过在MESFET应用中引入这两种透明材料,这种晶体管将在显示技术中特别有用,因为晶体管将不再阻挡光线。Mg0.3Zn0.7O的电阻为106 Ω/cm[3],可作为MESFET结构中的半绝缘材料,将其沉积在石英衬底上,然后在ZnO溶液中浸泡4.5小时。提前1天制备0.05M的ZnO溶液,搅拌加热后置于室温下,以获得更好的溶解度。这种化学浴沉积技术被认为是一种非常简单、低成本的技术,而且可以生产出非常均匀、排列的ZnO纳米棒。场发射扫描电镜(FESEM)显示,在Mg0.3Zn0.7O上成功生长出如图1所示的排列ZnO纳米棒,而Mg0.3Zn0.7O则以另一种方式促进了排列ZnO的更好生长。纳米棒的直径平均为75纳米,厚度约为1.6微米。x射线衍射谱显示,该排列的ZnO具有很强的(002)峰,在15°~ 60°之间,表明其结晶度较高。采用Keithley测量系统研究了ZnO/Mg0.3Zn0.7O异质结的IV响应。众所周知,使用不同的金属作为触点会导致不同的静脉反应行为。因此,我们使用了4种不同的金属来研究静脉注射反应。以金属化为目的,电子束蒸发器已被用于沉积铝、金、铂和镍作为金属触点。结果表明,由于每种金属的功函数不同,所选的4种金属具有不同的IV响应行为。为了研究排列ZnO/Mg0.3Zn0.7O异质结构的性能,以薄膜ZnO、薄膜ZnO/Mg0.3Zn0.7O和薄膜Mg0.3Zn0.7O的IV响应为参考。结果表明,与其他异质结构相比,排列ZnO/Mg0.3Zn0.7O异质结构具有更好的IV响应性能,本文将对此进行进一步讨论。由于该异质结构制作简单,且具有适合透明晶体管在显示技术中的应用的IV性能,因此可用于MESFET应用。
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