Nickel catalysis synthesis of 2,5-disubstituted furans from aryl (alkyl) iodide

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI:10.1080/10426507.2023.2249576
Zhongqiang Sun
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Abstract

A new methodology using various aryl(alkyl)iodides and CaC2 as coupling partners has been developed for the successful preparation of 2,5-disubstituted furans in good to excellent yields. The broad substrate range makes this method a practical and versatile approach for the preparation of (hetero)aryl- and alkyl-substituted furans, which are valuable building blocks in many biologically active compounds and functional materials.

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镍催化碘化芳基(烷基)合成 2,5-二取代呋喃
利用各种芳基(烷基)碘化物和 CaC2 作为偶联剂成功制备 2,5 二甲基呋喃的新方法已经开发出来,产率从良好到极佳。该方法的底物范围很广,是制备(杂)芳基和烷基取代呋喃的一种实用且多用途的方法。
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来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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