J. Fedotova, Uladzislaw E. Gumiennik, S. Vorobyova, M. M. Degtyarik, A. Kharchanka, J. Przewoźnik, C. Kapusta
{"title":"Phase composition and local environment of iron ions in gadolinium-doped iron oxide nanoparticles","authors":"J. Fedotova, Uladzislaw E. Gumiennik, S. Vorobyova, M. M. Degtyarik, A. Kharchanka, J. Przewoźnik, C. Kapusta","doi":"10.33581/2520-257x-2022-2-30-37","DOIUrl":null,"url":null,"abstract":"FeO ⋅ Fe2O3 ⋅ nH2O, Fe2.95Gd0.05O4 and Fe2.9Gd0.1O4 powders were obtained by chemical precipitation from aqueous solutions. The phase composition and local environment of iron ions in gadolinium-doped iron oxide nanoparticles were studied by X-ray diffraction analysis and nuclear gamma resonance (NGR) spectroscopy. Interpretation of radiographs and NGR spectra of synthesised samples indicates the presence of a superposition of maghemite γ-Fe2O3 and iron hydroxide α-FeOOH in the samples. It was found that under the deposition of powders in the presence of gadolinium nitrate, an increase in the content of iron hydroxide α-FeOOH is observed, which disappears after annealing at 200 °C.","PeriodicalId":17303,"journal":{"name":"Journal of the Belarusian State University. Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Belarusian State University. Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.33581/2520-257x-2022-2-30-37","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
FeO ⋅ Fe2O3 ⋅ nH2O, Fe2.95Gd0.05O4 and Fe2.9Gd0.1O4 powders were obtained by chemical precipitation from aqueous solutions. The phase composition and local environment of iron ions in gadolinium-doped iron oxide nanoparticles were studied by X-ray diffraction analysis and nuclear gamma resonance (NGR) spectroscopy. Interpretation of radiographs and NGR spectra of synthesised samples indicates the presence of a superposition of maghemite γ-Fe2O3 and iron hydroxide α-FeOOH in the samples. It was found that under the deposition of powders in the presence of gadolinium nitrate, an increase in the content of iron hydroxide α-FeOOH is observed, which disappears after annealing at 200 °C.