Phase composition and local environment of iron ions in gadolinium-doped iron oxide nanoparticles

J. Fedotova, Uladzislaw E. Gumiennik, S. Vorobyova, M. M. Degtyarik, A. Kharchanka, J. Przewoźnik, C. Kapusta
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Abstract

FeO ⋅ Fe2O3 ⋅ nH2O, Fe2.95Gd0.05O4 and Fe2.9Gd0.1O4 powders were obtained by chemical precipitation from aqueous solutions. The phase composition and local environment of iron ions in gadolinium-doped iron oxide nanoparticles were studied by X-ray diffraction analysis and nuclear gamma resonance (NGR) spectroscopy. Interpretation of radiographs and NGR spectra of synthesised samples indicates the presence of a superposition of maghemite γ-Fe2O3 and iron hydroxide α-FeOOH in the samples. It was found that under the deposition of powders in the presence of gadolinium nitrate, an increase in the content of iron hydroxide α-FeOOH is observed, which disappears after annealing at 200 °C.
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掺钆氧化铁纳米颗粒中铁离子的相组成和局部环境
采用化学沉淀法从水溶液中得到FeO⋅Fe2O3⋅nH2O、fe2.95 gd0.050 o4和fe2.9 gd0.10 o4粉末。采用x射线衍射分析和核伽马共振(NGR)技术研究了掺钆氧化铁纳米颗粒中铁离子的相组成和局部环境。合成样品的x光片和NGR光谱分析表明,样品中存在磁赤铁矿γ-Fe2O3和氢氧化铁α-FeOOH的叠加。结果表明,在硝酸钆存在下沉积粉末时,氢氧化铁α-FeOOH含量增加,在200℃退火后消失。
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