APPLICATION OF BARIUM-STRONTIUM CARBONATITE FOR PRODUCTION OF WELDING FLUXES BASED ON SILICOMANGANAZE PRODUCTION SLAG

N. Kozyrev, L. P. Bashchenko, O. Kozyreva, A. Mikhno
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Abstract

The study results of introduction of barium-strontium carbonatite of various fractional composition into flux based on silicomanganese production slag are presented. The principal possibility of using their mixtures for depositing and welding of low-alloy steels is shown, while the use of barium-strontium carbonatite makes it possible to reduce contamination of weld metal with nonmetallic inclusions. In series of experiments in laboratory conditions, various compositions of welding fluxes were made and investigated. As components, barium-strontium modifier BSC produced by “NPK Metallotechnoprom” LC under TU 1717-001-75073896-2005 was used, wt. %: 13.0 – 19.0 % BaO; 3,5 – 7,5 % SrO; 17.5 – 25.5 % CaO; 19.8 – 29.8 % SiO2 ; 0.7 – 1.1 % MgO; 2.5 – 3.5 % K2O; 1.0 – 2.0 % Na2O; 1.5 – 6.5 % Fe2O3 ; 0 to 0.4 % MnO; 1.9 – 3.9 % of Al2O3 ; 0.7 – 1.1 % TiO2 ; 16.0 – 20.0 % CO2 as well as silicomanganese slag produced by JSC “EVRAZ – West-Siberian Metallurgical Combine”, wt. %: 6.91 – 9.62 % Al2O3 ; 22.85 – 31.70 % CaO; 46.46 – 48.16 % SiO2 ; 0.27 – 0.81 % FeO; 6.48 – 7.92 % MgO; 8.01 – 8.43 % MnO; 0.28 – 0.76 % F; 0.26 – 0.36 % Na2O; up to 0,62 % K2O; 0.15 – 0.17 % S; 0.01 % P. Basis of the flux is silicomanganese production slag, into which a flux additive was introduced. Flux additive was produced in two ways. The first one: by mixing barium-strontium modifier with liquid glass in a ratio of 75 and 35 %, respectively. The second variant is as follows: dust of strontium-barium modifier of fraction less than 0.2 mm was used as a flux additive. The technology of flux-additive manufacturing is described. Welding of rollers was carried out using ASAW-1250 welding tractor. Regimes of surfacing were worked out. The chemical compositions of fluxes, slag crusts, flux and weld metal were determined. Metallographic studies of metal were performed. The results of analysis for presence of nonmetallic inclusions in weld zone were carried out in accordance with GOST 1778 – 70. Studies indicate a decrease in contamination of weld metal by silicates that are not deformed and absence of brittle silicates. 
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碳酸钡锶矿在硅锰锌生产渣生产焊剂中的应用
介绍了以硅锰生产渣为原料,将不同组分的钡锶碳酸盐引入助熔剂的研究结果。表明了使用它们的混合物沉积和焊接低合金钢的主要可能性,而使用钡锶碳酸盐可以减少非金属夹杂物对焊缝金属的污染。在实验室条件下进行了一系列的试验,研究了不同成分的焊剂。组分采用TU 1717-001-75073896-2005下“NPK Metallotechnoprom”LC生产的钡锶改性剂BSC, wt %: 13.0 - 19.0% BaO;3,5 - 7,5 % SrO;17.5 - 25.5% CaO;19.8 - 29.8% SiO2;0.7 - 1.1% MgO;2.5 - 3.5% k2o;1.0 - 2.0 % Na2O;1.5 - 6.5% Fe2O3;0 ~ 0.4% MnO;Al2O3含量1.9 ~ 3.9%;0.7 - 1.1% TiO2;JSC“EVRAZ -西西伯利亚冶金联合公司”生产的16.0 - 20.0% CO2和硅锰渣,重量%:6.91 - 9.62% Al2O3;22.85 - 31.70% CaO;46.46 - 48.16% SiO2;0.27 - 0.81% FeO;6.48 - 7.92% MgO;8.01 - 8.43% MnO;0.28 - 0.76% f;0.26 - 0.36% Na2O;高达0.62%的K2O;0.15 - 0.17% s;0.01% p,助熔剂的基础是硅锰生产渣,在渣中加入助熔剂添加剂。熔剂添加剂有两种生产方法。第一种方法:将钡锶改性剂与液态玻璃分别以75%和35%的比例混合。第二种变体是:采用分数小于0.2 mm的锶钡改性剂粉尘作为助熔剂添加剂。介绍了助焊剂增材制造技术。采用ASAW-1250焊接牵引车进行滚轮焊接。制定了表面处理制度。测定了焊剂、渣皮、焊剂和焊缝金属的化学成分。对金属进行了金相研究。根据GOST 1778 - 70对焊缝区非金属夹杂物进行了分析。研究表明,未变形的硅酸盐对焊缝金属的污染减少,并且没有脆性硅酸盐。
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来源期刊
Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya
Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya Materials Science-Materials Science (miscellaneous)
CiteScore
0.90
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0.00%
发文量
81
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