A model recovery process for scrap polystyrene foam by means of solvent systems

E.M. Kampouris, C.D. Papaspyrides, C.N. Lekakou
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引用次数: 34

Abstract

A solvent technique is studied for the recovery of polystyrene (PS) foam waste. The model process proposed ensures removal of any impurities present and comprises dissolution of the starting material, filtering, reprecipitation, thorough washing of the polymer grains obtained and drying. The solvent mixtures involved are separated by distillation for re-use. The following criteria are considered: (a) the rheological behaviour of the PS solutions prepared, (b) the yield of the process of polymer of acceptable grain size and (c) sufficient solvent/non-solvent separation. On the basis of these criteria, methyl ethyl ketone/n-hexane or methanol and p-xylene/n-heptane are suggested as effective solvent/non-solvent systems.

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采用溶剂系统回收废旧聚苯乙烯泡沫塑料的工艺模型
研究了用溶剂法回收聚苯乙烯(PS)泡沫废料的工艺。所提出的模型过程确保去除存在的任何杂质,包括起始物料的溶解、过滤、再沉淀、获得的聚合物颗粒的彻底洗涤和干燥。所涉及的溶剂混合物通过蒸馏分离以重新使用。考虑以下标准:(a)制备的PS溶液的流变行为,(b)可接受粒度的聚合物工艺的产率,以及(c)充分的溶剂/非溶剂分离。在此基础上,建议将甲乙基酮/正己烷或甲醇和对二甲苯/正庚烷作为有效的溶剂/非溶剂体系。
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