Liquid-Liquid Extraction of Zr(IV) from Sulphuric Acid Medium using Cyanex 923 in Kerosene

Jaykishon Swain, Amita R. Sahoo, Smrutiranjan Jena, B. Bhatta
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Abstract

The extraction behaviour of Zr(IV) from sulphuric acid with cyanex 923 (a mixture of four trialkyl phosphine oxides) in kerosene has been studied through a novel method liquid – liquid extraction. The mechanism of extraction and the species extracted have been identified. Quantitative extraction of Zr(IV) with cyanex 923 in kerosene was studied by changing different parameters such as acid variation, extractant variation, effect of salting out reagent concentration, effect of temperature, metal concentration variation and diluent effect. It was observed that the percentage of extraction of Zr(IV) increased when the concentrations of cyanex 923 and metal ion concentration increased. Kerosene was found to be effective diluent for the extraction of Zr(IV) withcyanex 923.
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用cyanex923液液萃取煤油中硫酸介质中的Zr(IV)
采用液-液萃取的新方法,研究了四种氧化三烷基膦的混合物氰ex923在煤油中从硫酸中萃取Zr(IV)的行为。对其提取机理和提取种类进行了鉴定。通过改变酸度变化、萃取剂变化、盐析剂浓度影响、温度影响、金属浓度变化和稀释剂影响等参数,研究了氰酸盐923在煤油中定量提取Zr(IV)的方法。结果表明,随着氰酸盐923浓度和金属离子浓度的增加,Zr(IV)的提取率增加。煤油是用氰ex923萃取Zr(IV)的有效稀释剂。
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