Larry W. Beck , Ping Lu , William P. Weber , Mark E. Davis
{"title":"Investigation of organosilanes as structure-directing agents in zeolite synthesis","authors":"Larry W. Beck , Ping Lu , William P. Weber , Mark E. Davis","doi":"10.1016/S0927-6513(97)00084-9","DOIUrl":null,"url":null,"abstract":"<div><p>MFI-type zeolites are synthesized with <em>N</em>-trimethoxysilylpropyl-<em>N,N,N</em>-trialkylammonium (TAASi) salts using the composition SiO<sub>2</sub>:0.1TAASiBr:0.25NaOH:40 H<sub>2</sub>O (molar ratios). Prehydrolysis of the organosilane precursor is necessary for zeolite formation. Quantitative NMR spectra show that the majority of the organsilicon carbon-silicon bonds are cleaved in the as-synthesized zeolite.</p></div>","PeriodicalId":100926,"journal":{"name":"Microporous Materials","volume":"12 4","pages":"Pages 361-368"},"PeriodicalIF":0.0000,"publicationDate":"1997-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0927-6513(97)00084-9","citationCount":"10","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927651397000849","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
Abstract
MFI-type zeolites are synthesized with N-trimethoxysilylpropyl-N,N,N-trialkylammonium (TAASi) salts using the composition SiO2:0.1TAASiBr:0.25NaOH:40 H2O (molar ratios). Prehydrolysis of the organosilane precursor is necessary for zeolite formation. Quantitative NMR spectra show that the majority of the organsilicon carbon-silicon bonds are cleaved in the as-synthesized zeolite.