Mikheev K. G., Syugaev A. V., Zonov R. G., Bulatov D. L., Mikheev G. M.
{"title":"Laser-induced graphene and its modification with polypyrrole for increasing microsupercapacitor capacitance","authors":"Mikheev K. G., Syugaev A. V., Zonov R. G., Bulatov D. L., Mikheev G. M.","doi":"10.21883/pss.2023.02.55422.529","DOIUrl":null,"url":null,"abstract":"Laser-induced graphene (LIG) films were synthesized by line-by-line scanning of cw CO2 laser focused radiation on the surface of industrial polyimide film as a result of pyrolysis of its near-surface layer. The structure of the synthesized film material is shown to be heterogeneous in thickness by Raman spectroscopy. The results of the study of the effect of the laser power and the distance between the lines on the specific electrical capacitance c of the synthesized material in aqueous solution of sulfuric acid are presented. It is shown that modification of LIG with polypyrrole (PPy) allows to increase c up to 60 mF/cm2. PPy-modified LIG films were used to make a prototype of a flexible film microsupercapacitor with an area of 8 cm2, using a gel electrolyte based on sulfuric acid and polyvinyl alcohol, with a 230 mF capacitance. Keywords: laser-induced graphene, electric capacitance, polypyrrole, microsupercapacitor.","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"416 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics of the Solid State","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.21883/pss.2023.02.55422.529","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 1
Abstract
Laser-induced graphene (LIG) films were synthesized by line-by-line scanning of cw CO2 laser focused radiation on the surface of industrial polyimide film as a result of pyrolysis of its near-surface layer. The structure of the synthesized film material is shown to be heterogeneous in thickness by Raman spectroscopy. The results of the study of the effect of the laser power and the distance between the lines on the specific electrical capacitance c of the synthesized material in aqueous solution of sulfuric acid are presented. It is shown that modification of LIG with polypyrrole (PPy) allows to increase c up to 60 mF/cm2. PPy-modified LIG films were used to make a prototype of a flexible film microsupercapacitor with an area of 8 cm2, using a gel electrolyte based on sulfuric acid and polyvinyl alcohol, with a 230 mF capacitance. Keywords: laser-induced graphene, electric capacitance, polypyrrole, microsupercapacitor.
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Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.
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