Oral Ingestion Risks of Heavy Metal Accumulation at Top Soils of Automobile Workshops in Owerri Capital City of Imo State, Nigeria

IF 0.4 Q4 CHEMISTRY, MULTIDISCIPLINARY Acta Chemica Iasi Pub Date : 2018-07-01 DOI:10.2478/achi-2018-0003
E. Agomuo, P. Amadi
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引用次数: 2

Abstract

Abstract This investigation was carried out to assess the heavy metal concentrations and health risks associated with automobile workshops in Owerri Metropolis. Using an Atomic Absorption Spectrophotometer, soil samples from Orji Mechanic Village (OMV), Naze Mechanic Village (NMV), New Market Automobile Workshops (NMAV), Matrix Mechanic Yard (MMY) and Alvan Mechanic Yard (AMY) were assayed for Silver (Ag), Cobalt (Co), Nickel (Ni), Mercury (Hg), Lead (Pb), Arsenic (As), Chromium (Cr) and Cadmium (Cd) concentrations. The result showed that at majority of the sites, the Ag, Pb, As, and Cd levels exceeded their baseline values, whereas the Ni and Co levels were equivalent to those of their baselines, at some sites. Soil samples at MMY were the most acidic while that of NMAV was the most alkaline. The pollution models indicated very high Ag contamination at OMV, NMV, and NMAV while all the sites showed very high contamination of Pb and Cd, and no Co, Ni, Hg, and Cr pollution was recorded for all the sites as shown by their Igeo values. The result for the enrichment factor showed anthropogenic sources of deposition of these heavy metals at all the sites. From the risk assessment models applied, none of the contaminated sites showed an estimated daily intake, hazard quotient, and total hazard index beyond the reference values, with Pb found to possess the greatest potentials of toxicity. This study has shown the necessity to periodically monitor and apply measures that can halt the environmental decay, occurring at the automobile workshops.
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尼日利亚伊莫州首府奥韦里市汽车车间表层土壤重金属的口服摄入风险
摘要本研究旨在评估奥韦里市汽车车间重金属浓度及其健康风险。采用原子吸收分光光度计对来自奥尔吉机械村(OMV)、纳泽机械村(NMV)、新市场汽车车间(NMAV)、矩阵机械场(MMY)和阿尔万机械场(AMY)的土壤样品进行了银(Ag)、钴(Co)、镍(Ni)、汞(Hg)、铅(Pb)、砷(As)、铬(Cr)和镉(Cd)的测定。结果表明,在大多数地点,银、铅、砷和镉的水平超过了基线值,而在一些地点,镍和钴的水平与基线值相当。MMY土壤样品酸性最强,NMAV土壤样品碱性最强。污染模型显示,在OMV、NMV和NMAV, Ag污染非常高,而所有站点的Pb和Cd污染都非常高,所有站点的Igeo值均未记录到Co、Ni、Hg和Cr污染。富集因子的结果表明,这些重金属在所有地点的沉积都有人为来源。从应用的风险评估模型来看,所有污染场地的日摄入量、危害商数和总危害指数均未超出参考值,Pb具有最大的毒性潜力。这项研究表明,有必要定期监测和采取措施,以制止发生在汽车车间的环境恶化。
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Acta Chemica Iasi
Acta Chemica Iasi CHEMISTRY, MULTIDISCIPLINARY-
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