Rheology: A feasible tool to assess the viscoelastic behavior of natural ingredients

Jhon Jairo Rojas Camargo
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Abstract

Rheology studies the flow and deformation of materials. Thus, the knowledge of the rheological and mechanical properties is important for product design, production, quality control, and for predicting shelf storage stability. Rheology studies can assist scientists in formulating optimal products (1). Conventionally, a single-point viscosity tests are widely used, but they not adequate in characterizing the full rheological profile of these materials, and thus, it is better to generate the full viscosity curves to capture a wide range of material responses (2). There are several tests conducted to characterize a material. The first one implies plotting viscosity as a function of a stress ramp at constant temperature and within a specific time interval. Usually, at low stresses viscosity might remain constant, and then a critical stress point is reached were viscosity decreases abruptly. The magnitude of the resulting slope confirms the shear sensitivity of the material (3). Another highly used plot involves the viscosity versus shear rate. Usually, at low shear rates viscosity remains constant and then it decreases steadily. Further, from the stress ramp test the minimum shear stress required to initiate flow (Yield stress) is determined. The higher the yield value, the more readily a dispersion will maintain particles in suspension with minimal sedimentation. However, a low yield stress might be useful for a product to improve the sensorial properties such as the ease of spreading onto a surface forming a short-term thin layer (4).
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流变学:一种评估天然成分粘弹性行为的可行工具
流变学研究材料的流动和变形。因此,流变学和机械性能的知识是重要的产品设计,生产,质量控制,并预测货架储存稳定性。流变学研究可以帮助科学家制定最佳产品(1)。传统上,单点粘度测试被广泛使用,但它们不足以表征这些材料的完整流变特性,因此,最好生成完整的粘度曲线,以捕获广泛的材料响应(2)。有几个测试进行表征材料。第一种方法是在一定的温度下,在一定的时间间隔内,将粘度绘制为应力斜率的函数。通常,在低应力下,黏度可能保持恒定,然后达到一个临界应力点,黏度突然下降。所得斜率的大小证实了材料的剪切敏感性(3)。另一个经常使用的图表涉及粘度与剪切速率的关系。通常,在低剪切速率下,粘度保持恒定,然后稳定下降。此外,从应力斜坡试验中确定了启动流动所需的最小剪切应力(屈服应力)。屈服值越高,分散体就越容易使颗粒保持悬浮状态,沉降最小。然而,低屈服应力可能有助于提高产品的感官性能,如易于扩散到表面形成短期薄层(4)。
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