{"title":"Quenched-in Vacancies in Molybdenum","authors":"M. Suezawa, H. Kimura","doi":"10.1080/14786437308220991","DOIUrl":null,"url":null,"abstract":"Abstract Annealing experiments on quenched-in vacancies were performed with specially prepared high-purity molybdenum wire. The recovery stage was found to be centred at about 370°C, and the activation energy for the recovery was determined to be (1.62 ± 0.27) eV. The activation energy is tentatively considered to be the activation energy for the migration of single vacancies. With the activation energy, the loss of vacancies during quenching was discussed. The loss at the surface is found to be predominant. Correction for this loss was applied to the previously reported quenched-in resistivity results, and the formation energy of a vacancy was redetermined to be (3.24 ± 0.09) eV. These results are discussed in comparison with data on tungsten.","PeriodicalId":21586,"journal":{"name":"Science reports of the Research Institutes, Tohoku University. Ser. A, Physics, chemistry and metallurgy","volume":"52 1","pages":"158"},"PeriodicalIF":0.0000,"publicationDate":"1973-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"37","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science reports of the Research Institutes, Tohoku University. Ser. A, Physics, chemistry and metallurgy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/14786437308220991","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 37

Abstract

Abstract Annealing experiments on quenched-in vacancies were performed with specially prepared high-purity molybdenum wire. The recovery stage was found to be centred at about 370°C, and the activation energy for the recovery was determined to be (1.62 ± 0.27) eV. The activation energy is tentatively considered to be the activation energy for the migration of single vacancies. With the activation energy, the loss of vacancies during quenching was discussed. The loss at the surface is found to be predominant. Correction for this loss was applied to the previously reported quenched-in resistivity results, and the formation energy of a vacancy was redetermined to be (3.24 ± 0.09) eV. These results are discussed in comparison with data on tungsten.
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钼中的淬火空位
摘要:采用特制的高纯钼丝对淬火空位进行了退火实验。发现回收阶段集中在370℃左右,回收的活化能为(1.62±0.27)eV。我们暂时认为活化能是单个空位迁移的活化能。利用活化能,讨论了淬火过程中空位的损失。发现地表的损失占主导地位。对这一损失进行了校正,并将其应用于之前报道的淬火电阻率结果,并重新确定了空位的形成能为(3.24±0.09)eV。这些结果与钨的数据进行了比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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