Discharge electrolysis in molten chloride: formation of fine silver particles

Hiroyuki Kawamura , Kimikazu Moritani , Yasuhiko lto
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引用次数: 47

Abstract

A relatively stationary discharge was generated in molten chloride utilizing a simple apparatus and successfully achieved at electrolysis. Fine silver particles were obtained using a LiCl-KCl-AgCl eutectic melt in an argon atmosphere. SEM observations of the silver particles showed them to be almost spherical and the size to be strongly dependent on the experimental conditions. This new kind of discharge electrolysis is expected to be adopted as a new method for metal powder production.

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在熔融氯化物中放电电解:形成细银颗粒
利用简单的装置在熔融氯化物中产生相对稳定的放电,并在电解中成功地实现了放电。用LiCl-KCl-AgCl共晶熔体在氩气气氛中获得了细小的银颗粒。对银颗粒的扫描电镜观察表明,它们几乎是球形的,其大小与实验条件密切相关。这种新型放电电解技术有望成为金属粉末生产的一种新方法。
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