Sergei V. Volkov, Nikolai I. Buryak, Victor A. Bandur
{"title":"Metal-complex catalysis of oxidation of saturated hydrocarbons in melts","authors":"Sergei V. Volkov, Nikolai I. Buryak, Victor A. Bandur","doi":"10.1016/S1288-3255(00)01022-4","DOIUrl":null,"url":null,"abstract":"<div><p>The structure of melts and the role in them of 3<em>d</em>-metal coordination polyhedra as oxygenated metal complexes for the catalytic oxidation of saturated hydrocarbons has been elucidated using electronic absorption spectroscopy (EAS), ESR and mass-spectroscopy. The direct partial oxidation of methane to methanol and formaldehyde in sodium metaphosphate melts containing 3<em>d</em>-metal ions has been studied. It has been shown for the oxidation of isopropyl alcohol that the catalytic activity of these melts increases when there are two 3<em>d</em>-metal coordination centers in them.</p></div>","PeriodicalId":101031,"journal":{"name":"Plasmas & Ions","volume":"3 1","pages":"Pages 53-63"},"PeriodicalIF":0.0000,"publicationDate":"2000-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1288-3255(00)01022-4","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasmas & Ions","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1288325500010224","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The structure of melts and the role in them of 3d-metal coordination polyhedra as oxygenated metal complexes for the catalytic oxidation of saturated hydrocarbons has been elucidated using electronic absorption spectroscopy (EAS), ESR and mass-spectroscopy. The direct partial oxidation of methane to methanol and formaldehyde in sodium metaphosphate melts containing 3d-metal ions has been studied. It has been shown for the oxidation of isopropyl alcohol that the catalytic activity of these melts increases when there are two 3d-metal coordination centers in them.
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