Study on Uniaxial Elongational Viscosity and Vacuum Molding Processability of the PP/PE Blends

S. Shiromoto, Taro Miyazawa, K. Koyama
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Abstract

The relationship between uniaxial elongational viscosity and vacuum molding processability of the PP/PE blends were investigated. Propylene homo-polymer (PP) and 3 kinds of high pressure method low density polyethylene with different molecular weight (PE-A, PE-B, PE-C) were used. Materials were melt blended to the ratio of PP/PE=90/10, 80/20 and 70/30wt% for the experiments. The PP/PE blends showed strain hardening of uniaxial elongational viscosity, while PP showed no strain hardening. The strain hardening of PP/PE increased with increasing of the blend ratio of PE to PP, and the molecular weight of PE. The morphologies of PP/PE under uniaxial elongational flow were observed by TEM. For the samples with the lower molecular weight PE, the larger deformation of PE domain was observed. The deviation of thickness of the vacuum molding products decreased according to the increase of the strain hardening of PP/PE.
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PP/PE共混物单轴拉伸粘度及真空成型加工性研究
研究了PP/PE共混物的单轴拉伸粘度与真空成型加工性的关系。采用丙烯均聚物(PP)和3种不同分子量的高压法低密度聚乙烯(PE-A、PE-B、PE-C)。实验采用PP/PE=90/ 10,80 /20和70/30wt%的熔体共混。PP/PE共混物表现出单轴拉伸黏度的应变硬化,而PP没有表现出应变硬化。随着PE与PP共混比的增大和PE分子量的增大,PP/PE的应变硬化程度增大。用透射电镜观察了PP/PE在单轴拉伸流作用下的形貌。对于PE分子量较低的样品,PE畴变形较大。随着PP/PE应变硬化量的增加,真空成型制品的厚度偏差减小。
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