Uranyl - PyridylAzo Resorcinol System: Uncertainty Budget Evaluation and Interference Elimination

S. Chandramouleeswaran, J. Ramkumar
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Abstract

The spectrophotometric determination of uranyl ion with 4-(2-Pyridylazo)resorcinol (PAR) is a well known and old method. However this technique gives scope for further research in order to make it more selective as well as sensitive for uranyl ion determination. In this study, the experimental protocol has simplified as compared to previous report. An attempt to evaluate the uncertainty budget associated with the determination has been carried out. The effect of different cationic interferences has been studied and a simple method was developed to reduce the interferences.
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铀酰-吡啶偶氮间苯二酚体系:不确定度预算评估及干扰消除
4-(2-吡啶偶氮)间苯二酚(PAR)分光光度法测定铀酰离子是一种众所周知的古老方法。然而,该技术为进一步研究提供了空间,以使其对铀酰离子的测定更具选择性和敏感性。在本研究中,实验方案与以往的报道相比有所简化。本文尝试评价与确定相关的不确定度预算。研究了不同阳离子干扰的影响,提出了一种降低阳离子干扰的简单方法。
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