Effect of Harum Manis mango as natural photosensitizer at different extracting temperature on performance of dye-sensitized solar cells (DSSCs)

S. Suhaimi, M. Shahimin, S. Z. Siddick, B. Razak, M. H. C. Mat
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引用次数: 2

Abstract

Dye-sensitized solar cells containing yellow curcumin of Harum Manis mango were extracted in water and ethanol solvent and fabricated at different temperatures to find the optimum condition with the best performance solar cell. Harum Manis mango was studied as an alternative sensitizer, that anchored to a nanoparticle titanium dioxide scaffold, due to its availability in native Malaysia climate. The absorption spectrum of each dye was measured using ultraviolet-visible spectroscopy. The absorption spectrum shows an absorption peak at 450nm in water and a broader absorption in the ethanol. The conversion efficiency achieved by dyes extracted in water and ethanol solvent at room temperature is about 0.03% and 0.51%. When temperature parameter is varied (room temperature, 50°C, 75°C, and 100°C), dye extracted in water solvent attains its highest efficiency of about 0.60% and 0.32% in ethanol at 50°C. In fact, 50°C extracting temperature in water solvent shows as an optimum condition for Harum Manis mango to achieve its best performance. This paper reveals detailed optimization of fabrication process at different extracting temperatures for Harum Manis mango photosensitizer based solar cells which can be used as an environmental friendly, low cost alternative system especially for further research in DSSCs technology.
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芒果作为天然光敏剂在不同提取温度下对染料敏化太阳能电池性能的影响
以芒果黄姜黄素为原料,分别在水和乙醇溶剂中提取染料敏化太阳能电池,并在不同温度下制备太阳能电池。Harum Manis芒果被研究作为一种替代敏化剂,它被固定在纳米二氧化钛支架上,因为它在马来西亚本土气候中是可用的。采用紫外-可见光谱法测定各染料的吸收光谱。在水中有450nm处的吸收峰,在乙醇中有较宽的吸收峰。在室温条件下,用水和乙醇提取染料的转化率分别为0.03%和0.51%。当温度参数变化(室温、50℃、75℃、100℃)时,在水溶剂中提取的染料效率最高,约为0.60%,在50℃乙醇中提取的效率最高,约为0.32%。事实上,50°C的水溶剂提取温度是获得芒果最佳性能的最佳条件。本文对芒果光敏剂太阳能电池在不同提取温度下的制备工艺进行了详细的优化,该电池可作为一种环境友好、低成本的替代系统,特别是在DSSCs技术的进一步研究中。
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