Polystyrene‐supported aluminium silver chloride as selective ethylene adsorbent

H. Hirai, S. Hara, M. Komiyama
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引用次数: 20

Abstract

Polystyrene-supported aluminium silver chloride was prepared as a solid and selective adsorbent for ethylene by refluxing silver chloride, aluminium chloride, and macroreticular-type polystyrene resin in carbon disulfide, followed by removal of the solvent in vacuo. The adsorbent rapidly adsorbed ethylene about equimolar to aluminium silver chloride under 1 atm at 20°C. Almost all the ethylene adsorbed was released by subjecting the adsorbent to a reduced pressure 8 mm Hg at 20°C for 10 min. The adsorbent, however, showed no adsorption of carbon monoxide under 1 atm at 20°C.
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聚苯乙烯负载氯化铝银作为选择性乙烯吸附剂
通过将氯化银、氯化铝和大孔型聚苯乙烯树脂在二硫化碳中回流,真空脱除溶剂,制备了聚苯乙烯负载型氯化铝银作为乙烯的固体选择性吸附剂。吸附剂在20℃下,在1atm下将等摩尔的乙烯快速吸附到氯化铝银上。在20℃下,将吸附剂减压8 mm Hg,持续10 min,几乎所有吸附的乙烯都被释放。然而,在20℃下,吸附剂在1 atm下没有吸附一氧化碳。
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