Resistance to Sulphate and Acid Attack of Rice Husk Ash and Fly Ash Based Composite Cement

Md Ershad Halim, Kazi Nasrin Farooque, Mohammed Mahmudul Hasan, Md. Hasanur Rahman, Uzzal Shaha, F. Ferdousi, Umme Sarmeen Akhtar, M. Ismail, M. Akramuzzaman
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Abstract

The current exploration work contains the preparation and examination of the properties of cement-based composite materials. Two kinds of composite materials specifically, Rice Husk Ash Composite Cement and Fly Ash Composite Cement were examined. Rice Husk Ash Composite Cement and Fly Ash Composite Cement was treated with Na2SO4 and HCl solution to check the resistance towards sulphate and acid attack respectively. Sulfate attack has been resolved in this work by estimating weight loss/gain of Ordinary Portland Cement (OPC) and the Composite Cements created from FA and RHA when plunged into 0.5 M and 0.75 M Na2SO4 solution. A loss in weight has been seen at the underlying stage i.e. Following 7 and 14 days when OPC is immersed in sulfate media, however, in the long run there was gain in weight of the composite made with OPC. The loss of weight occurred when the entire test sample is treated with 1.0 M HCl. Results on acid resistance and sulphate attack revealed that Composite cements are better acid resistant but more susceptible to sulphate attack. It was also observed that FAC composite is more susceptible to sulphate attack than RHAC composite. The Ca(OH)2 leaching tests indicate that Composite Cements are effective in reducing the amount of Ca(OH)2 leaching compared to pristine OPC. Dhaka Univ. J. Sci. 71(1): 49-55, 2023 (Jan)
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稻壳灰和粉煤灰基复合水泥的抗硫酸盐和酸侵蚀性能
目前的勘探工作包括水泥基复合材料的制备和性能测试。具体考察了稻壳灰复合水泥和粉煤灰复合水泥两种复合材料的性能。用Na2SO4和HCl溶液分别对稻壳灰复合水泥和粉煤灰复合水泥进行处理,考察其抗硫酸盐和酸侵蚀性能。本研究通过估算普通硅酸盐水泥(OPC)和由FA和RHA制成的复合水泥在0.5 M和0.75 M Na2SO4溶液中的失重/增重,解决了硫酸盐侵蚀问题。在底层阶段,即在OPC浸泡在硫酸盐介质中7天和14天后,可以看到重量减轻,然而,从长远来看,用OPC制成的复合材料重量增加。当整个试验样品用1.0 M盐酸处理时,发生重量损失。结果表明,复合水泥具有较好的耐酸性能,但易受硫酸盐侵蚀。FAC复合材料比RHAC复合材料更容易受到硫酸盐侵蚀。Ca(OH)2浸出试验表明,与原始OPC相比,复合水泥可以有效减少Ca(OH)2的浸出量。达卡大学学报(自然科学版),71(1):49- 55,2023 (1)
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