Composition of heavy paraffinic oil from the Rechitsa field and pyrolysis oil obtained from rubber waste

T. Henarava, S. M. Leschev, A. A. Kartuzava
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Abstract

The problem of alternative sources of hydrocarbon fuels is currently of great importance. The constant growth of organopolymer waste, in particular, automobile tires, has stimulated the search for ways to recycle them. It was found that a promising method of their processing is pyrolysis in various modes [1]. A comprehensive study of the composition and properties of the resulting pyrolysis oils obtained from used tires will make it possible to find out the possibility of their use as a secondary raw material for the production of hydrocarbon fuels. In this work, the component composition of heavy paraffinic oil from the Rechitsa field and pyrolysis oil obtained during the thermal treatment of rubber products in a nitrogen atmosphere, by methods of IR spectroscopy, elemental and GC-MS analysis, has been investigated. In addition, their fractional composition, density of fractions, as well as iodine number have been determined. Based on the results obtained, conclusions were drawn about the similarities and differences between pyrolysis oil and petroleum. It has been suggested that liquid pyrolysis products, after appropriate treatment, can be used as additives to petroleum products, which contributes not only to solving the problems of both the disposal of used tires, but also the depletion of readily available oil reserves.
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Rechitsa油田重石蜡油和橡胶废料热解油的组成
碳氢化合物燃料的替代来源问题目前是一个非常重要的问题。有机聚合物废物的不断增长,特别是汽车轮胎,刺激了寻找回收它们的方法。发现多种模式热解是一种很有前途的处理方法[1]。对从废旧轮胎中获得的热解油的成分和性质进行全面研究,将有可能发现它们作为生产碳氢化合物燃料的二次原料的可能性。本文采用红外光谱、元素分析和气相色谱-质谱分析等方法,对Rechitsa油田重石蜡油和橡胶制品在氮气气氛下热处理过程中得到的热解油的组分进行了研究。此外,还测定了它们的分数组成、分数密度和碘值。在此基础上,总结了热解油与石油的异同。有人建议,液体热解产物经过适当处理后,可以作为石油产品的添加剂,这不仅有助于解决废旧轮胎的处理问题,而且有助于解决现有石油储量的枯竭问题。
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38
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