Photocatalytic reduction of nitro aromatic compounds to their corresponding amino aromatic compounds by rGO/ZnFe2O4 under visible light irradiation

Leila Masti, A. Bezaatpour, N. Bozari, Y. Azizian-Kalandaragh
{"title":"Photocatalytic reduction of nitro aromatic compounds to their corresponding amino aromatic compounds by rGO/ZnFe2O4 under visible light irradiation","authors":"Leila Masti, A. Bezaatpour, N. Bozari, Y. Azizian-Kalandaragh","doi":"10.22075/CHEM.2021.21751.1914","DOIUrl":null,"url":null,"abstract":"In this research work, the rGO/ZnFe2O4 photocatalyst was prepared by hydrothermal method and characterized and identified using X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), field emission scanning electron microscope (FE-SEM), Diffuse Reflectance Spectroscopy (DRS), vibrating-sample magnetometer (VSM), surface area analysis (BET) and Energy-dispersive X-ray spectroscopy (EDAX) techniques. The photocatalyst was used for the reduction of nitroaromatic compounds to their corresponding aromatic amines with hydrazine monohydrate. The catalyst showed the best activity in the reduction of 1,4-dinitrobenzen (%97 conversion in 40 min). The recyclability and reusability of the catalyst was evaluated for four times which showed no significant variation in the conversion of nitrobenzene photoreduction reaction.","PeriodicalId":7954,"journal":{"name":"Applied Chemistry","volume":"17 1","pages":"109-122"},"PeriodicalIF":0.0000,"publicationDate":"2021-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22075/CHEM.2021.21751.1914","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

In this research work, the rGO/ZnFe2O4 photocatalyst was prepared by hydrothermal method and characterized and identified using X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), field emission scanning electron microscope (FE-SEM), Diffuse Reflectance Spectroscopy (DRS), vibrating-sample magnetometer (VSM), surface area analysis (BET) and Energy-dispersive X-ray spectroscopy (EDAX) techniques. The photocatalyst was used for the reduction of nitroaromatic compounds to their corresponding aromatic amines with hydrazine monohydrate. The catalyst showed the best activity in the reduction of 1,4-dinitrobenzen (%97 conversion in 40 min). The recyclability and reusability of the catalyst was evaluated for four times which showed no significant variation in the conversion of nitrobenzene photoreduction reaction.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
rGO/ZnFe2O4在可见光下光催化还原硝基芳香族化合物为相应的氨基芳香族化合物
本研究采用水热法制备了rGO/ZnFe2O4光催化剂,并利用x射线粉末衍射(XRD)、傅里叶变换红外光谱(FT-IR)、场发射扫描电镜(FE-SEM)、漫反射光谱(DRS)、振动样品磁强计(VSM)、表面积分析(BET)和能量色散x射线能谱(EDAX)等技术对rGO/ZnFe2O4光催化剂进行了表征。该光催化剂用于硝基芳香族化合物与一水合肼还原成相应的芳胺。该催化剂对1,4-二硝基苯的还原活性最佳(40 min转化率为97%)。对催化剂的可回收性和可重复使用性进行了4次评价,对硝基苯光还原反应的转化率无显著影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
One pot three component synthesis of 2-amino-4H-chromene derivatives under microwave irradiation using Sr2As2O7 nanocatalyst Green and three-component synthesis of 2-cyclohexylamino-2-oxo-1-arylethyl/alkyl thiophene-3-carboxylates in aqueous medium Photocatalytic reduction of nitro aromatic compounds to their corresponding amino aromatic compounds by rGO/ZnFe2O4 under visible light irradiation Extraction of Active Ingredients from Shiraz City Bitter Orange Peel with supercritical carbon dioxide and soxhlet Measuring of metanephrine by UV-Vis peak of surface absorption Plasmon resonance of silver nanoparticles by response surface methodology
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1