THERMODYNAMIC ANALYSIS OF HIGHLY TOXIC EFFLUENTS NEUTRALIZATION PROCESS

V. Korzhyk, V. Kolesnyk, V. Orlyk, V. Shevchenko, S. Kostash
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Abstract

Thermodynamic analysis of the high-toxic substances (hydrazine, dimethylhydrazine and dinitrogen tetroxide) thermal decomposition process contained in liquid mixtures in different concentrations was carried out. Calculations of equilibrium compositions were carried out in a wide temperature range for a steam-water plasmatron. The aim of the study was finding the operational parameter’s optimal range of values ensuring the complete decomposition of primary high-toxic components provided secondary harmful substances minimal formation and obtaining acceptance level of specific energy consumption. The methods of further harmful secondary emissions neutralization have been determined. Bibl. 9, Fig. 7.
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剧毒废水中和过程的热力学分析
对不同浓度液体混合物热分解过程中含有的高毒物质(肼、二甲肼和四氧化二氮)进行了热力学分析。在较宽的温度范围内对蒸汽-水等离子体进行了平衡成分的计算。研究的目的是寻找操作参数的最佳取值范围,保证一次高毒成分完全分解,同时保证二次有害物质的最小生成,并获得比能耗的可接受水平。确定了进一步消除有害二次排放的方法。圣经第九章,图七章。
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