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COMPARATIVE ANALYSIS OF THE EFFICIENCY OF WATER AND WATER-AMINE ABSORPTION PROCESSES FOR EXTRACTING CO2 FROM BIOGAS 水吸收法和水胺吸收法从沼气中提取二氧化碳的效率比较分析
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.02
Yu.V. Ivanov, H. Zhuk, L. Onopa, S.P. Krushnevych
The production of biomethane from biogas energy costsfor the most widely used amine and water processes for extracting carbon dioxide from biogas were analyzed using computer simulation. Combined water-amine absorption method of biogas purification from CO2 wasincluded in the comparative analysis. For the CO2 content of the biogas from 32 to 42 %, the specific energy costs when using water absorption to extract carbon dioxide from biogas are, on average, in ~ 2.5 times lower than amine absorption, but the loss of CH4 by water absorption was 7.1–7.6 % due to its watersolubility with practically zero CH4 loss when using amine absorption and insignificant loss (0.17–2.8 %) using water-amine technology. Using preliminary water absorption of CO2 saved CH4 can compensate the power consumption of the biogas compressor or the heatcosts of saturated amine absorbent regenerating. This will allowto reduce energy consumption to almost equal to water absorptionone. The results of simulation of carbon dioxide extraction from biogas can be used to optimize technological absorption schemes for the production of biomethane — an analogueof natural gas. Bibl. 13, Fig. 5, Tab. 6.
利用计算机模拟分析了目前应用最广泛的从沼气中提取二氧化碳的氨法和水法生产生物甲烷的能源成本。采用水胺联合吸附法对CO2净化沼气进行了对比分析。在CO2含量为32% ~ 42%的范围内,吸水法提取二氧化碳的比能成本平均比胺法低2.5倍,但由于其水溶性,吸水法的CH4损失为7.1 ~ 7.6%,胺法的CH4损失几乎为零,而水胺法的CH4损失不显著(0.17 ~ 2.8%)。利用预吸水的CO2节省的CH4可以补偿沼气压缩机的功耗或饱和胺吸收剂再生的热成本。这将允许减少能源消耗,几乎等于水的吸收1。从沼气中提取二氧化碳的模拟结果可用于优化生产生物甲烷的技术吸收方案。生物甲烷是一种天然气的类似物。圣经13,图5,表6。
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引用次数: 2
STATE AND PROSPECTS OF THERMAL POWER GENERATION IN THE CONDITIONS OF UKRAINE’S COURSE ON CARBON-FREE ENERGY 乌克兰无碳能源进程条件下火力发电的现状和前景
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.01
M. Cherniavskyi
The structure of electricity cost formation for consumers, including depending on the cost of TPP generation, «green» energy and other sources, is investigated, and the main conditions of the efficient regulatory function fulfillment in the power system by thermal power generation in the conditions of Ukraine's course on carbon-free energy are formulated. It is shown that excessive electricity losses in networks and, especially, accelerated increase of the share of «green» generation, much more expensive than nuclear, hydro and thermal, mainly contribute to the growth of electricity costs for non-household consumers and the need to raise tariffs for the population. This accelerated increase directly contradicts the Paris Climate Agreement, according to which plans to reduce Ukraine’s greenhouse gas emissions must be developed taking into account available energy resources and without harming its own economy. The dependences of the specific fuel consumption on the average load and the frequency of start-stops of units are found and it is shown that the increased specific fuel consumption on coal TPPs is an inevitable payment for their use as regulating capacities of UES of Ukraine. In this case, the higher the proportion of «green» generation and a smaller proportion of generating thermal power plants, especially increasing specific fuel consumption. It is proved that in the conditions of growth of the share of «green» generation in Ukraine the share of production of pulverized coal thermal power plants should be kept at the level of not less than 30 % of the total electricity generation. It is substantiated that a necessary condition for coal generation to perform a proper regulatory role in the power system is to introduce both environmental and technical measures, namely — reducing the suction of cold air to the furnace and other boiler elements, restoring condensers and cooling systems, etc. An important factor in reducing the average level of specific fuel consumption is also the reduction of coal burn-out at thermal power plants, where it still remains significant, due to the transfer of power units to the combustion of bituminous coal concentrate. Bibl. 12, Fig. 5, Tab. 5.
研究了消费者的电力成本形成结构,包括取决于TPP发电成本,“绿色”能源和其他来源,并制定了乌克兰无碳能源进程条件下,火力发电在电力系统中有效履行监管职能的主要条件。研究表明,电网的过度电力损失,特别是“绿色”发电份额的加速增长,比核能、水力和热能贵得多,主要是造成非家庭消费者电力成本增长和提高人口电价的需要。这种加速增长直接与巴黎气候协议相矛盾,根据该协议,减少乌克兰温室气体排放的计划必须考虑到可用的能源资源,并且不损害其自身的经济。发现了比燃料消耗与机组平均负荷和启停频率的依赖关系,并表明煤电厂比燃料消耗的增加是其作为乌克兰UES调节能力的不可避免的支付。在这种情况下,“绿色”发电比例越高,火力发电厂的发电比例越小,特别是增加了比燃料消耗。事实证明,在乌克兰“绿色”发电份额增长的条件下,煤粉火力发电厂的生产份额应保持在不低于总发电量30%的水平。事实证明,煤炭发电在电力系统中发挥适当调节作用的必要条件是引入环境和技术措施,即减少对炉膛和其他锅炉元件的冷空气吸力,恢复冷凝器和冷却系统等。减少特定燃料消耗平均水平的一个重要因素也是减少火力发电厂的烧煤,由于动力装置改用燃烧烟煤浓缩物,烧煤仍然很严重。圣经12,图5,表5。
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引用次数: 3
OBTAINING AND PROPERTIES OF NANOSCALE SOLID-STATE HEAT STORAGE WITH CARNAUBA WAX 巴西棕榈蜡纳米固态储热材料的制备及性能研究
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.04
S. Brichka
Latent thermal energy storage using phase change materials has attracted interest in the use of solar and other types of energy due to their ability to provide high density lateral energy storage. Materials with a latent heat of storage have become attractive for their use in many branches of human activity. However, the materials use is often limited by problems of low thermal conductivity, the transition from a solid to a molten state causes difficulties in storing materials in a container, and special heat exchangers are needed to increase the energy cost. The solution to the above problems may be to create solid-state, form-stable heat storage elements. In this work, a number of shape-stable materials with a phase transition were obtained from melts by mixing halloysite nanotubes with carnauba wax in order to improve the heat accumulation characteristics. Halloysite nanotubes were mixed at elevated temperatures with carnauba melted wax and rapidly cooled to prevent the nanotubes sedimentation. As a result, a series of solid wax/nanotube samples were prepared with weight ratios of 70/30, 60/40 and 50/50. Pure wax showed a accumulation heat of the solid-to-liquid phase transition of 189.09 J/g. Carnauba wax has a latent heat greater by about 25 % compared to paraffin. Composite materials had significantly lower latent heat, respectively, 99.39 J/g for 70/30, 90.25 J/g for 60/40, and 81.26 J/g for 50/50 samples. Elemental mapping of the nanomaterial revealed a nanotubes uniform distribution in the wax. According to the data of X-ray analysis, as a result of the composite materials preparation, the components did not form new crystalline phases, but they were physical mixtures. When heated, the components did not chemically interact with each other, which is useful for the accumulation of thermal energy by materials. Analysis of the IR spectra of the samples confirmed the change in the absorption bands of functional hydroxyl groups at 3696 sm–1 (Al–O–H) and 3621 sm–1 (Si–O–H). In primary nanotubes, the intensities ratio of silanol to aluminol groups is greater than unity, while in the composite it is already less than this value. This manifestation can be explained by the fact that, during the wax melting, the interaction of wax molecules on the outer surface of the nanotubes occurs. Bibl. 16, Fig. 5.
利用相变材料的潜热储能由于其提供高密度横向储能的能力,已经引起了人们对太阳能和其他类型能源使用的兴趣。具有储存潜热的材料因其在人类活动的许多部门中的应用而变得具有吸引力。然而,材料的使用往往受到低导热性问题的限制,从固体到熔融状态的转变导致材料在容器中存储困难,并且需要特殊的热交换器来增加能源成本。解决上述问题的方法可能是制造固态的、形式稳定的储热元件。本研究通过将高岭土纳米管与巴西棕榈蜡混合,获得了一些具有相变的形状稳定材料,以改善其蓄热特性。高岭土纳米管在高温下与巴西棕榈熔化的蜡混合,并迅速冷却以防止纳米管沉积。制备了质量比分别为70/30、60/40和50/50的固体蜡/纳米管样品。纯蜡的固液相变积累热为189.09 J/g。巴西棕榈蜡的潜热比石蜡大25%左右。复合材料的潜热分别为:70/30、60/40和50/50样品的潜热分别为99.39 J/g、90.25 J/g和81.26 J/g。纳米材料的元素映射显示纳米管均匀分布在蜡中。根据x射线分析数据,由于复合材料的制备,各组分没有形成新的晶相,而是物理混合物。加热时,组件之间不会发生化学相互作用,这对材料积累热能很有用。红外光谱分析证实了3696 sm-1 (Al-O-H)和3621 sm-1 (Si-O-H)官能团吸收带的变化。在原生纳米管中,硅烷醇与铝醇基团的强度比大于1,而在复合材料中,硅烷醇与铝醇基团的强度比已经小于1。这种现象可以解释为,在蜡熔化过程中,蜡分子在纳米管的外表面发生了相互作用。圣经16,图5。
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引用次数: 1
THERMOHYDRAULIC DISTRIBUTION IN TWISTED MICRO HEAT EXCHANGERS MOUNTED IN ANNULAR CHANNELS 安装在环形通道中的螺旋微型热交换器的热液分布
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.07
V. Tuz, N. Lebed
The design of twisted heat exchangers provides a possibility to compensate for temperature and mechanical stresses thus ensuring continuous and failsafe operation of the equipment. The authors use fins and multiturn pipe bundles to reduce the mass and size characteristics of the heat exchangers. Such design significantly complicates the calculating method. The main aspect of swirling flows is the presence of radial and axial pressure gradients. When vapor or gas flows swirl, the flow velocity near the walls is much higher than the average values, while at the axis the flow is significantly slower and in some cases its values can become negative. The liquid flowing near the axis has a notably lower pressure, which can cause it to boil. Considerable radial gradients of axial and rotational speed, as well as static pressure contribute to turbulent pulsations. Given that the working fluid flows along a helical line, the flow in the near-wall area is similar to the flow around curved surfaces. The study analyses how the pipe bundle geometry impacts hydraulic distribution and scrutinizes the main components of pressure loss in the twisted heat exchanger. The analysis allowed simplifying the method of hydraulic calculation of the multiturn twisted heat exchanger. Solving the outer heat transfer and hydrodynamics problem for the twisted heat exchanger allowed determining the effect of the main factors and the relationship between the parameters of the coolant and the working mass on the distribution values. The paper presents the equations for determining geometry of the pipes with different coiling diameters, as well as the equation for finding hydraulic distribution in individual pipes in the layers of the pipe bundle. The obtained results can help increase the accuracy of thermal calculation. The authors propose to use sectioning of twisted heat exchangers as a way to reduce hydraulic distribution. Bibl. 12, Fig. 1.
扭曲式热交换器的设计提供了补偿温度和机械应力的可能性,从而确保设备的连续和故障安全运行。作者采用翅片和多匝管束来减小换热器的质量和尺寸特性。这样的设计大大复杂化了计算方法。旋流的主要方面是径向和轴向压力梯度的存在。当蒸汽或气体旋转流动时,壁面附近的流速远高于平均值,而在轴线处的流速明显较慢,在某些情况下其值可以变为负值。在轴附近流动的液体具有明显较低的压力,这可能导致液体沸腾。相当大的轴向和旋转速度的径向梯度以及静压有助于湍流脉动。考虑工作流体沿螺旋线流动,近壁面区域的流动类似于曲面周围的流动。分析了管束几何形状对扭流式换热器水力分布的影响,分析了扭流式换热器压力损失的主要组成部分。通过分析,简化了多匝扭流式换热器的水力计算方法。通过对双绞线换热器的外传热和流体力学问题的求解,可以确定主要因素以及冷却剂参数和工作质量之间的关系对其分布值的影响。本文给出了确定不同卷取直径管道几何形状的公式,以及确定管束各层中单个管道的水力分布的公式。所得结果有助于提高热计算的精度。作者建议采用双绞线换热器分段的方式来减少水力分配。圣经12,图1
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引用次数: 2
STUDY OF THE OXIDATION PROCESS OF NITROGEN OXIDES BY OZONE 臭氧氧化氮氧化物过程的研究
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.06
I. Volchyn, O. M. Kolomiets, S. Mezin, A. Yasynetskyi
The need to reduce emissions of pollutants, in particular nitrogen oxides, as required by regulations in Ukraine, requires the use of modern technologies and methods for waste gas treatment at industrial enterprises. This is especially true of thermal power plants, which are powerful sources of nitrogen oxide emissions. The technological part of the wet or semi-dry method of purification is the area for the oxidation of nitrogen oxides to obtain easily soluble compounds. The paper presents the results of a study of the process of ozone oxidation of nitrogen oxides in a chemical reactor. Data for the analysis of the process were obtained by performing physical experiments on a laboratory installation and related calculations on a mathematical model. Studies of the oxidation process have shown that the required amount of ozone depends not only on the content of nitrogen monoxide, but also on the content of nitrogen dioxide. The process of conversion of nitrogen monoxide to a satisfactory level occurs at the initial value of the molar ratio of ozone to nitrogen monoxide in the range of 1.5…2. The conversion efficiency of nitrogen monoxide reaches 90% at a gas temperature less than 100 °C. To achieve high conversion efficiency at gas temperatures above 100 °C, it is necessary to increase the initial ozone content when the molar ratio exceeds 2. The analysis shows that the conversion efficiency of nitric oxide largely depends on the residence time of the gas mixture in the reaction zone. Due to lack of time under certain conditions, the efficiency decreases by approximately 46%. To increase it, it is necessary to accelerate the rate of oxidation reactions due to better mixing of gases by turbulence of the flow in the oxidizing reactor. Bibl. 6, Fig. 6, Tab. 3.
根据乌克兰条例的要求,必须减少污染物,特别是氮氧化物的排放,这就要求在工业企业中使用现代技术和方法处理废气。对于火力发电厂来说尤其如此,它们是氮氧化物排放的重要来源。湿法或半干法净化的技术部分是氧化氮氧化物以获得易溶化合物的区域。本文介绍了在化学反应器中臭氧氧化氧化氮氧化物过程的研究结果。分析该过程的数据是通过在实验室装置上进行物理实验和在数学模型上进行相关计算获得的。氧化过程的研究表明,臭氧的需要量不仅取决于一氧化氮的含量,而且取决于二氧化氮的含量。在臭氧与一氧化二氮摩尔比的初始值在1.5…2范围内,一氧化二氮的转化过程达到满意的水平。当气体温度低于100℃时,一氧化氮的转化效率可达90%。为了在100℃以上的气体温度下获得较高的转化效率,必须在摩尔比超过2时提高初始臭氧含量。分析表明,一氧化氮的转化效率在很大程度上取决于气体混合物在反应区的停留时间。在某些条件下,由于缺乏时间,效率下降约46%。为了提高它,有必要通过氧化反应器中的湍流更好地混合气体来加速氧化反应的速率。圣经6,图6,表3。
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引用次数: 0
ENERGY EFFICIENT EQUIPMENT FOR MODERNIZATION OF THE GAS BOILERS POWER 0.1-30 MW 节能设备的现代化燃气锅炉功率0.1-30兆瓦
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.03
I. Sigal, E. M. Lavrentsov, A. Smikhula, O. Marasin, E.P. Dombrovska
The possibility of modernization of boilers TVH-8M, TVH-8 and NYYSTU-5, operated in Ukraine, with the increasing of their technical and economic indicators to the modern European level is shown. Projects of modernization of boilers have been developed, which consist in redesign of heating surfaces in convective shafts of existing boilers without increasing their overall dimensions with using convective part of pipes diameter 32 x 3 mm and replacement of burner devices by developed new type MPIG-3. It is shown that the results of industrial implementations achieved efficiency of boilers type TVH-8M (TVH-8) 94-96% in the operating range of their load and obtained the calculated efficiency for boilers NYYSTU-5 92-94%. It is experimentally proven that when installing special calibrated nozzle, instead of drilled holes in the collectors of gas burners, it is possible to keep the nozzle geometry (natural gas burner consumption depending on pressure) unchanged throughout the service life. The technical possibility of combustion of biogas and mixtures of natural gas and hydrogen in the slot bottom diffusion burners of the MPIG-3 type, when replacing only the nozzle apparatus is shown. Bibl. 17, Fig. 6, Table 1.
显示了在乌克兰运行的锅炉TVH-8M, TVH-8和NYYSTU-5现代化的可能性,其技术和经济指标提高到现代欧洲水平。开发了锅炉现代化项目,其中包括在不增加锅炉整体尺寸的情况下,重新设计现有锅炉对流轴的受热面,使用直径为32 x 3毫米的管道对流部分,并用开发的新型MPIG-3替换燃烧器装置。工业实施结果表明,TVH-8M (TVH-8)型锅炉在负荷运行范围内的效率为94 ~ 96%,NYYSTU-5型锅炉的计算效率为92 ~ 94%。实验证明,当安装特殊的校准喷嘴时,而不是在燃气燃烧器的集热器上钻孔,可以在整个使用寿命中保持喷嘴几何形状(天然气燃烧器消耗取决于压力)不变。展示了仅更换喷嘴装置时,在MPIG-3型槽底扩散燃烧器中燃烧沼气和天然气与氢气混合物的技术可能性。圣经17,图6,表1。
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引用次数: 0
A STATE OF ART AND PROSPECTS OF HANDLING USED PET BOTTLES 废旧宠物瓶处理技术现状及展望
Pub Date : 2021-12-20 DOI: 10.33070/etars.4.2021.05
I. Mikulionok
The main data on the production volume of bottles from polyethylene terephthalate (PET) in the world are presented. The main ways of handling used PET bottles as one of the hazardous types of waste for the environment, but promising from the point of view of using their properties, are analyzed. The main methods of handling used PET bottles are considered and a critical analysis of each of them is given. Particular attention is paid to the methods of recycling PET bottles, which made it possible to efficiently use recycled PET raw materials directly for their intended purpose. The features of physical, chemical, biological and combined processing methods are also considered, in particular, combustion, gasification, pyrolysis, plasma decomposition of PET bottles, as well as their decomposition under the influence of microorganisms. The main ways of solving the problem of used PET bottles are proposed.  Bibl. 84, Fig. 1.
介绍了世界上聚乙烯对苯二甲酸乙二醇酯(PET)瓶产量的主要数据。废旧PET瓶是一种危害环境的废弃物,从利用其特性的角度分析了处理废旧PET瓶的主要方法。考虑了处理废旧PET瓶的主要方法,并对每种方法进行了批判性分析。特别关注回收PET瓶的方法,这使得有效地将回收的PET原料直接用于其预期用途成为可能。还考虑了物理、化学、生物和组合处理方法的特点,特别是燃烧、气化、热解、等离子体分解PET瓶,以及它们在微生物影响下的分解。提出了解决废旧PET瓶问题的主要途径。圣经第84章,图1
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引用次数: 2
MODELING OF A DUSTED GAS FLOW CLEANING PROCESS USING A KINEMATIC MODEL OF THE INTERACTION OF DISPERSED PARTICLES WITH DROPLETS IN A WET SCRUBBER 用湿式洗涤器中分散颗粒与液滴相互作用的运动学模型对含尘气流清洗过程进行建模
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.07
I. Volchyn, V. Raschepkin
A mathematical model is proposed for the scavenging process of the dispersed particles by droplets in a wet scrubber under excess spray density in Venturi tube within kinematic approach of the interaction of particles in countercurrent gas-dispersed flows, which refines the existing engineering model, taking into account the spatial size variation of the droplets, due to their coagulation with wet slurry droplets and uncaptured particles entering a wet scrubber from the Venturi tube. The results of calculations with the adopted mathematical model showed that in case of possibility to organize the spraying of a gas flow in a scrubber with 300–500 micron droplets aerosol at a specific spray density of about 1 liter/m3, a 1–2 meters wide layer of droplets ensures effective absorption of both uncaptured PM2.5 solid particles, and the slurry droplets from the Venturi tube. The ejection of the slurry droplets into a wet scrubber from the Venturi tube, and the associated increase in the size of the scrubber droplets due to coagulation with slurry droplets, does not noticeably affect the efficiency of the dusted gas stream cleaning. An adopted mathematical model was applied to calculate the capture of particles by droplets in cylindrical and conical scrubbers. Due to the increase in a residence time of the droplets upon increased velocity of the countercurrent gas flow, the efficiency of gas cleaning from dispersed particles in a conical scrubber appears to be higher than in a cylindrical scrubber. However, with an increase in the spray density above 2 liter/m3 and with droplet diameters greater than 1000 microns, the efficiency of the conical scrubber decreases, which is associated to an increase in the escape of a significant proportion of massive drops to the walls with a reduction in the scrubber reactor cross-section.  Bibl. 21, Fig. 4.
基于逆流气体分散流中颗粒相互作用的运动学方法,提出了在文丘里管超喷雾密度条件下湿式洗涤器中液滴对分散颗粒的清除过程的数学模型,该模型考虑了液滴与湿浆状液滴和从文丘里管进入湿式洗涤器的未捕获颗粒的混凝而产生的空间尺寸变化,对现有的工程模型进行了改进。利用所采用的数学模型进行计算的结果表明,在有可能用300-500微米的雾滴以1升/m3左右的比喷雾密度组织洗涤塔内的气流喷射时,1 - 2米宽的雾滴层既可以有效吸收未捕获的PM2.5固体颗粒,也可以有效吸收文丘里管中的浆状雾滴。浆液液滴从文丘里管喷射到湿式洗涤器中,以及由于与浆液液滴混凝而导致洗涤器液滴尺寸的增加,对含尘气流清洗的效率没有明显影响。应用所采用的数学模型计算了圆柱和锥形洗涤器中液滴对颗粒的捕获。由于液滴的停留时间随着逆流气流速度的增加而增加,锥形洗涤器中分散颗粒的气体净化效率似乎高于圆柱形洗涤器。然而,当喷雾密度大于2升/m3时,当液滴直径大于1000微米时,锥形洗涤器的效率降低,这与大量大液滴逃逸到壁上的比例增加有关,同时洗涤器反应器截面减小。圣经21,图4。
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引用次数: 0
INVESTIGATION OF THE PROCESS OF OBTAINING PYROCARBON IN AN ELECTROTHERMAL FLUIDIZED BED 电热流化床制焦碳工艺研究
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.03
K. Simeyko, A. Malinouski, S. Karsim, M. Sydorenko, A. Kustovska, O. Liaposhchenko, S. V. Kupriyanchuk
Carbon materials with a wide range of performance properties are used in various science, technology, and industry fields. For example, Pyrocarbon has the prospect of being used in nuclear power engineering, special metallurgy, aerospace technologies, heat exchange equipment, medicine, mechanical engineering, reactor building and other industries. The research described in the article aims to study the process of obtaining pyrocarbon in an electrothermal fluidized bed. The research is based on experimental methods of studying the process of obtaining pyrolytic carbon. Pyrocarbon is precipitated during pyrolysis (thermal destruction) of hydrocarbons in an electrothermal fluidized bed reactor. Natural gas was used as a fluidizing agent, and crushed fine electrode graphite of the GE model was used as a fluidized bed. When producing batches of pyrocarbon material, taking into account that the particle size will increase, these particles were crushed and subsequently used as a fluidized bed, thereby replacing graphite with pyrocarbon. As a result of the experimental studies carried out in the reactor with the electrothermal fluidized bed reactor, the batches of pyrocarbon material that were produced based on artificial graphite were produced. Studies using electron microscopy showed a change in the color and structure of the pyrocarbon coating depending on the processing cycle in the electrothermal fluidized bed reactor at temperatures of 900–1200 °C. Diffractometric analysis showed that pyrocarbon was identified in the treated material. Therefore, the adequacy of the method for calculating the heat balance has been confirmed. Bibl. 36, Fig. 7, Table 1.
碳材料具有广泛的性能,广泛应用于各种科学、技术和工业领域。例如,焦碳在核电工程、特种冶金、航天技术、换热设备、医药、机械工程、反应堆建造等行业具有应用前景。本文研究的目的是研究在电热流化床中获得焦碳的过程。本研究以实验方法为基础,研究了热解碳的制备过程。在电热流化床反应器中,烃类在热解(热破坏)过程中会析出焦碳。以天然气为流化剂,GE模型细电极石墨破碎为流化床。在生产成批的焦碳材料时,考虑到颗粒尺寸会增大,将这些颗粒粉碎后用作流化床,从而用焦碳代替石墨。利用电热流化床反应器在反应器内进行了实验研究,生产出了以人造石墨为原料生产的成批热解炭材料。电镜研究表明,在900-1200℃的电热流化床反应器中,随着处理周期的不同,热解炭涂层的颜色和结构发生了变化。衍射分析表明,在处理后的材料中发现了焦碳。因此,证实了计算热平衡方法的充分性。圣经36,图7,表1。
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引用次数: 0
COMPARISON OF GAZKONDNAFTA AND HYSYS SOFTWARE SYSTEMS IN THE FIELD OF COMPUTER MODELING OF OIL AND GAS TECHNOLOGIES gazkondnafta和hysys软件系统在油气技术计算机建模领域的比较
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.01
O. V. Kalashnikov, S. Budniak, Yu.V. Ivanov, Yu.M. Belyansky, N. O. Aptulina, A. O. Zobnin
The experimental and calculated according to program systems GasCondOil, Aspen-HYSYS and PRO-II compositions of the gas — liquid phases (hydrocarbon and aqueous solutions) and their thermodynamic properties are compared, as well as the accuracy of technological calculations of field pipelines and natural gas and oil treatment processes. It is shown that some of the field technological processes, calculated by the program system GasCondOil, are not modeled on Aspen-HYSYS. Bibl. 16, Fig. 9, Tab. 15.
对比了GasCondOil、Aspen-HYSYS和PRO-II程序系统计算的气液相(烃类和水溶液)组成和热力学性质,以及现场管道和油气处理工艺计算的准确性。结果表明,用GasCondOil程序系统计算的一些现场工艺过程不能在Aspen-HYSYS上建模。圣经16,图9,表15。
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引用次数: 2
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Energy Technologies & Resource Saving
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