Heterocyclic 1,3-diazepine-based thiones and selones as versatile halogen-bond acceptors

Arianna C. Ragusa, Andrew J. Peloquin, Marjan M. Shahani, Keri N. Dowling, J. Golen, C. McMillen, D. Rabinovich, W. Pennington
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Abstract

Utilizing the N-heterocyclic chalcogenones hexahydro-1,3-bis(2,4,6-trimethylphenyl)-2H-1,3-diazepine-2-thione (SDiazMesS) and hexahydro-1,3-bis(2,4,6-trimethylphenyl)-2H-1,3-diazepine-2-selone (SDiazMesSe) as halogen-bond acceptors, 24 new cocrystals were prepared. The solid-state structures of the parent molecules were also determined, along with those of their acetonitrile solvates.
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杂环1,3-二氮卓类硫酮和硒酮作为多用途卤素键受体
利用n-杂环硫基因六氢-1,3-二(2,4,6-三甲基苯基)- 2h -1,3-二氮卓-2-硫酮(SDiazMesS)和六氢-1,3-二(2,4,6-三甲基苯基)- 2h -1,3-二氮卓-2-selone (SDiazMesSe)作为卤素键受体,制备了24个新的共晶。测定了母体分子及其乙腈溶剂化物的固态结构。
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Chalcogen Chemistry: Fundamentals and Applications. Edited by Vito Lippolis, Claudio Santi, Eder J. Lenardão and Antonio L. Braga. Royal Society of Chemistry, 2023. Hardcover, pp. 728. Price EUR 156.00. ISBN 978-1-83916-422-4 Synthesis and structure of high-purity BaCe0.25Mn0.75O3: an improved material for thermochemical water splitting Preparation and crystallographic characterization of 1H-tetrazole/NaClO4 energetic cocrystal Evolution of intermolecular contacts with temperature and pressure in bromoethane and iodoethane – a comparative study Design of a series of cocrystals featuring isoniazid modified with diacetone alcohol
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