Kinetic Study of the Reversible Hydroxide Addition Reaction to a Hexafluoro-2,4-pentanedionato Chelate on a Cobalt(III) Complex

Abstract

*Corresponding author. kitamura@chem.sci.ehime-u.ac.jp † The abbreviations for ligands are: Hhfac = hexafluoro-2,4-pentanedione; MeNH2 = methylamine; EtNH2 = ethylamine; en = ethylenediamine; tn = 1,3-propanediamine; trien = 1,8-diamino-3,6-diazaoctane; tren = 2,2’,2”-triaminotriethylamine; trpn = 3,3’,3”triaminotripropylamine; cyclam = 1,4,8,11-tetraazacyclotetradecane; dien = diethylenetriamine; H(i-dtma) = N,N-bis(2-aminoethyl)glycine; H(5-dptma) = N,N-bis(3-aminopropyl)glycine; H2(edda) = ethylenediamine-N,N’-diacetic acid; H2(aeida) = N-(2-aminoethyl)-N(carboxymethyl)glycine; and H3(nta) = nitrilotriacetic acid. Inorganic Reaction Mechanisims, Vol. 5, pp. 213-230 © 2005 Old City Publishing, Inc. Reprints available directly from the publisher Published by license under the OCP Science imprint, Photocopying permitted by license only a member of the Old City Publishing Group.