{"title":"Oxidation of ε-Aminocaproic Acid by Bis(dihydrogentellurato)argentite(III): A Kinetics and Mechanism Study","authors":"S. Huo, C. Song","doi":"10.1515/IRM.2008.6.4.313","DOIUrl":null,"url":null,"abstract":"The oxidation ofε-aminocaproic acid by the Ag(III) complex, bis(dihydrogen tellurato)argentite(III) was studied by the stopped-flow method. It was both first order with respect to Ag(III) complex and ε-aminocaproic acid. A plausible mechanism involving a pre-equilibrium adduct formation between the Ag(III) complex and ε-aminocaproic acid was proposed from the kinetics study. The rate law derived from the mechanism can explain all experimental phenomena. The activation parameters along with rate constants were calculated.","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2008-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"BioInorganic Reaction Mechanisms","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/IRM.2008.6.4.313","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The oxidation ofε-aminocaproic acid by the Ag(III) complex, bis(dihydrogen tellurato)argentite(III) was studied by the stopped-flow method. It was both first order with respect to Ag(III) complex and ε-aminocaproic acid. A plausible mechanism involving a pre-equilibrium adduct formation between the Ag(III) complex and ε-aminocaproic acid was proposed from the kinetics study. The rate law derived from the mechanism can explain all experimental phenomena. The activation parameters along with rate constants were calculated.
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