Catalyst Enhanced by Controlling Structure and Shape of Nanocrystals, Support Materials, and Hybrid System in DMFCs

Young Wook Lee, T. Shin
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Abstract

s Direct methanol fuel cells (DMFCs) have found a wide variety of commercial applications such as portable computer and mobile phone. In a fuel cell, the catalysts have an important role and durability and efficiency are determined by the ability of the catalyst. The activity of the catalyst is determined by the structure and shape control of the nanoparticles and the dispersion of the nanoparticles and application system. The surface energy of nanoparticles determines the activity by shape control and the nanostructure is determined by the ratio of biand tri-metals in the alloy and core-shell. The dispersion of nanoparticles depends on the type of support such as carbon, graphen and metal oxide. In addition, a hybrid system using both optical and electrochemical device has been developed recently.
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纳米晶体、支撑材料和混合体系对dmfc催化剂结构和形状的控制
直接甲醇燃料电池(dmfc)已经有了广泛的商业应用,如便携式电脑和移动电话。在燃料电池中,催化剂起着重要的作用,催化剂的性能决定了电池的耐久性和效率。催化剂的活性取决于纳米颗粒的结构和形状控制以及纳米颗粒的分散和应用体系。纳米粒子的表面能通过形状控制来决定活性,纳米结构由合金中双金属和三金属与核壳的比例决定。纳米粒子的分散取决于载体的类型,如碳、石墨和金属氧化物。此外,最近还开发了一种采用光学和电化学装置的混合系统。
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