Synthesis and Characterization of 5-Chloro 2-furaldehyde Thiosemicarbazone and Its Nickel, Copper and Zinc Complexes

Mohammed Adam Adam Abdulbary, M. S. A. Eltoum, E. Ali
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Abstract

The aim of the present study was to synthesize and characterize of divalent metal ions of Nickel, Copper and Zinc complexes of 5-chloro 2-furaldehyde thiosemicarbazone. Firstly ligand was prepared from the reaction between 5-Chloro-2-furaldehyde and thiosemicarbazide, the second step involved the synthesis of Ni(II), Cu(II) and Zn(II) complexes of 5-chloro 2-furaldehyde thiosemicarbazone. The prepared compounds (ligand or complex) was characterized using different analytical techniques such as elemental analysis, and IR, UV, Mass and 1H NMR tests, the results obtained showed that the ligand and its Ni(II), Cu(II), Zn(II) and Co(II) complexes of 5-chloro 2-furaldehyde thiosemicarbazone were prepared successfully.
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5-氯- 2-呋喃醛硫代氨基脲及其镍、铜、锌配合物的合成与表征
本研究的目的是合成镍、铜、锌二价金属离子的5-氯- 2-呋喃醛硫代氨基脲配合物并对其进行表征。首先由5-氯-2-呋喃醛与硫代氨基脲反应制备配体,第二步合成5-氯-2-呋喃醛硫代氨基脲的Ni(II)、Cu(II)和Zn(II)配合物。采用元素分析、红外光谱、紫外光谱、质谱和核磁共振氢谱等方法对所制备的配合物(配体或配合物)进行了表征,结果表明,所制备的5-氯- 2-呋喃醛硫代氨基脲配体及其Ni(II)、Cu(II)、Zn(II)和Co(II)配合物均制备成功。
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