{"title":"Preparation Of A Chiral Cu(II)-Schiff Base Complex And Application For Asymmetric Catalysis","authors":"Leman Alkan","doi":"10.7212/ZKUFBD.V8I1.921","DOIUrl":null,"url":null,"abstract":"A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized reaction conditions.","PeriodicalId":17742,"journal":{"name":"Karaelmas Science and Engineering Journal","volume":"57 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Karaelmas Science and Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.7212/ZKUFBD.V8I1.921","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized reaction conditions.
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