Optoelectronic Evaluation, Chemical Potential Identification, Chemiparametric Oscillation Mapping, and Dielectric Efficiency Investigation of Organic NLO Crystal: 2‐Aminofluorene Using Computational Calculations

IF 1.5 4区 材料科学 Q3 CRYSTALLOGRAPHY Crystal Research and Technology Pub Date : 2021-06-22 DOI:10.1002/crat.202100062
Ramalingam Thirumurugan, Singaravelu Ramalingam, S. Periandy., R. Aarthi
{"title":"Optoelectronic Evaluation, Chemical Potential Identification, Chemiparametric Oscillation Mapping, and Dielectric Efficiency Investigation of Organic NLO Crystal: 2‐Aminofluorene Using Computational Calculations","authors":"Ramalingam Thirumurugan, Singaravelu Ramalingam, S. Periandy., R. Aarthi","doi":"10.1002/crat.202100062","DOIUrl":null,"url":null,"abstract":"In this work, the semi‐organic, 2‐aminofluorene single‐crystal is grown by slow evaporation method. The crystal is optimized and determination of optical axis and the crystal sample is characterized. The volume of the crystal is 568.22 Å3and density −1.311 mg cm−3. The XRD parameters estimate crystal lattice as orthorhombic. The birefringence effect is measured with inter‐atomic attractive dispersion forces. The rearrangement of molecular frame of fluorine on par with amino substitution is estimated. The electro‐optic effect is established by parametric oscillations of accumulation of chemical potential to enable the mechanism of nonlinear optical (NLO) effect. The dielectric loss with respect to the temperature/electrical frequency and the active optical property is measured. The amino group causes optical scattering of nodal regions for radiation absorption process to fascinate optical endurance. The chemical energy processing to acquire the chemical potential to operate light frequency amplification is thoroughly studied from the observation of chemical shift over the molecular frame. The oscillated parametric energy on nonbonding molecular orbital (NBMO) is initiated by the NH2group on the ring carbon–carbon (CC) and it is exchanged among nodal zones of core and comprised of the above segments of the ring.","PeriodicalId":10797,"journal":{"name":"Crystal Research and Technology","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2021-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Research and Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/crat.202100062","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0

Abstract

In this work, the semi‐organic, 2‐aminofluorene single‐crystal is grown by slow evaporation method. The crystal is optimized and determination of optical axis and the crystal sample is characterized. The volume of the crystal is 568.22 Å3and density −1.311 mg cm−3. The XRD parameters estimate crystal lattice as orthorhombic. The birefringence effect is measured with inter‐atomic attractive dispersion forces. The rearrangement of molecular frame of fluorine on par with amino substitution is estimated. The electro‐optic effect is established by parametric oscillations of accumulation of chemical potential to enable the mechanism of nonlinear optical (NLO) effect. The dielectric loss with respect to the temperature/electrical frequency and the active optical property is measured. The amino group causes optical scattering of nodal regions for radiation absorption process to fascinate optical endurance. The chemical energy processing to acquire the chemical potential to operate light frequency amplification is thoroughly studied from the observation of chemical shift over the molecular frame. The oscillated parametric energy on nonbonding molecular orbital (NBMO) is initiated by the NH2group on the ring carbon–carbon (CC) and it is exchanged among nodal zones of core and comprised of the above segments of the ring.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
有机NLO晶体:2 -氨基芴的光电评价、化学势识别、化学参数振荡映射和介电效率研究
本文采用慢蒸发法制备了半有机2 -氨基芴单晶。对晶体进行了优化,并对光轴的测定和晶体样品进行了表征。晶体体积为568.22 Å3and,密度为−1.311 mg cm−3。XRD参数估计晶体晶格为正交晶格。双折射效应是用原子间吸引色散力测量的。估计氟分子框架的重排与氨基取代相当。电光效应是通过化学势积累的参数振荡来实现非线性光学效应的机制。测量了介质损耗与温度/电频率和有源光学特性的关系。氨基引起辐射吸收过程中节点区域的光散射,从而影响光持久度。从分子框架上的化学位移观察出发,深入研究了获得化学势操作光频放大的化学能处理过程。非键分子轨道(NBMO)上的振荡参数能量由环上的碳-碳(CC)上的nh2基团引发,并在核心节点区之间交换,由上述环段组成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
6.70%
发文量
121
审稿时长
1.9 months
期刊介绍: The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing
期刊最新文献
Characterization of Elastic Constants of Langatate Single Crystals with 32 Symmetry Using Ultrasonic Pulse‐Echo Technique Adhesion, Stability and Electronic Properties of Ag/SnO2 Interface from First‐Principles Calculation Determination of Thermal Properties of Carbon Materials above 2000 °C for Application in High Temperature Crystal Growth Development of the VGF Crystal Growth Recipe: Intelligent Solutions of Ill‐Posed Inverse Problems using Images and Numerical Data Masthead: Crystal Research and Technology 12'2021
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1