{"title":"Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex","authors":"Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty","doi":"10.1515/irm-2003-0109","DOIUrl":null,"url":null,"abstract":"Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"10 1","pages":"73 - 78"},"PeriodicalIF":0.0000,"publicationDate":"2003-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"BioInorganic Reaction Mechanisms","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/irm-2003-0109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.
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