Synthesis and Crystallization Kinetics of Y 2CaA1 4SiO 12 Garnet-Type Glass-Ceramic

Liyuan Wang, Jiaxi Liu, N. Lu, Zeng-chao Yang, G. He, Xiaoyu Li, Jianqiang Li, Jiangtao Li
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Abstract

Y2CaA14SiO12 garnet-type glass-ceramic was obtained by heat-treatment of the bulk glass with corresponding composition, which fabricated by aerodynamic levitation coupled with a laser heating system. The crystallization kinetics of the glass was investigated via Differential Scanning Calorimetry (DSC). The effects of heat-treatment temperature on the phase, microstructure, mechanical and optical properties of the Y2CaA14SiO12 garnet-type glass-ceramic were also systemically studied. The crystallization mechanism of this Y2CaA14SiO12 glass is three-dimensional growth followed with surface and inner nucleation. With the increasing of heat-treatment temperature, the density and hardness increased, while transparency declined as a result of rapid grain growth.
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y2caa1 - 4sio12石榴石型玻璃陶瓷的合成及结晶动力学
采用气动悬浮耦合激光加热系统,对含有相应成分的块状玻璃进行热处理,得到了Y2CaA14SiO12石榴石型玻璃陶瓷。用差示扫描量热法(DSC)研究了玻璃的结晶动力学。系统研究了热处理温度对Y2CaA14SiO12石榴石型微晶玻璃的物相、显微组织、力学性能和光学性能的影响。Y2CaA14SiO12玻璃的结晶机制是三维生长,然后是表面成核和内部成核。随着热处理温度的升高,合金的密度和硬度增加,晶粒生长迅速,透明度下降。
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