Effect of unsaturated polyester concentration on rheological characteristics of polypropylene-unsaturated polyester reactive blend

G. M. Mamoor, M. N. Khan, Asad Ali, S. Shahid, M. Iqbal
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Abstract

Reactive blends of polypropylene and unsaturated polyester with different compositions were prepared by melt processing using dicumyl peroxide (DCP) as initiator in a plasticoder. Rheological Characteristics of the blends were studied as a function of unsaturated polyester concentration over a range of strain rate. The possibility of forming a graft polymer increased with increasing the unsaturated polyester content. Change in viscosity behavior of the blends was a result of the competing reactions of degradation and grafting. Keywords: DCP; strain rate; degradation; grafting DOI = 10.3329/cerb.v14i2.5955 Chemical Engineering Research Bulletin 14 (2010) 105-108
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不饱和聚酯浓度对聚丙烯-不饱和聚酯反应共混物流变特性的影响
采用熔融法制备了不同组分的聚丙烯和不饱和聚酯共混物,并以过氧化二氨基(DCP)为引发剂。在应变速率范围内,研究了共混物的流变特性与不饱和聚酯浓度的关系。随着不饱和聚酯含量的增加,形成接枝聚合物的可能性增加。共混物粘度行为的变化是降解和接枝反应相互竞争的结果。关键词:DCP;应变率;退化;DOI = 10.3329/cerb.v14i2.5955化学工程研究通报14 (2010)105-108
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