Effect of Surfactant Addition on Organic Transparent Conductive Films Fabricated by Inkjet Printing Method

Atsushi Nitta, Naohiko Chosa, K. Takeda
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引用次数: 1

Abstract

Recently, active research has been conducted on the development of flexible electronic devices. Hence, the transparent conductive film (TCF), an essential component of the device, must also be flexible. However, the commonly used indium tin oxide (ITO) TCF lacks flexibility and contains rare metal, making resource depletion an issue. Therefore, we focused on poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), which has high flexibility and conductivity. Flexible TCFs have been fabricated by coating PEDOT:PSS on polyethylene naphthalate substrates using an inkjet printer. However, the current issue in such fabrication is the effect of the interface state on the transparency and conductivity of the thin film. In this study, we investigated the effect of surfactant in addition to polar solvents on the properties of thin films fabricated with PEDOT:PSS ink. Although the electrical conductivity was reduced, the transmittance remained above 90%. Thus, these results are comparable to those of ITO TCFs for practical use in terms of optical properties.
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表面活性剂对喷墨印刷法制备有机透明导电薄膜的影响
近年来,人们对柔性电子器件的发展进行了积极的研究。因此,作为器件基本组成部分的透明导电膜(TCF)也必须具有柔性。然而,常用的氧化铟锡(ITO) TCF缺乏柔韧性,且含有稀有金属,使资源枯竭成为一个问题。因此,我们重点研究了具有高柔韧性和导电性的聚(3,4-乙烯二氧噻吩)/聚(苯乙烯磺酸酯)(PEDOT:PSS)。利用喷墨打印机在聚萘二甲酸乙二醇酯基板上涂覆PEDOT:PSS制备了柔性tcf。然而,目前的问题是界面状态对薄膜透明度和导电性的影响。在本研究中,我们研究了表面活性剂和极性溶剂对PEDOT:PSS油墨薄膜性能的影响。虽然电导率降低,但透光率保持在90%以上。因此,就光学性质而言,这些结果与实际使用的ITO tcf相当。
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