Effect of ultrasound exposure on melts of polyolefin compositions

Irina Krish, D. Pomogova, I. Tveritnikova, O. Beznaeva, O. Bannikova, V. Romanova, Daria M. Zagrebina
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Abstract

This study aimed at investigating the dependence of the ultrasonic (US) effects on the structure and properties of the polymer mixtures with different viscosity values. It should be noted that in the current study, polypropylene and high-pressure polyethylene of different brands were selected. The polymer composite materials (PCM) of various compositions treated with and without ultrasound were used. The formation dependence of the phase structures of polyolefin compositions on composition and viscosity of polymer systems was established. The regularity "structure-properties" of modified mixtures of polyolefins was determined. The influence of ultrasonic on the restoration process of the structure and the formation of new chemical bonds in polyolefin mixtures was discussed. The structure of the compositions of the polymer and technological conditions for their processing, which providing high physical and mechanical characteristics of PCM, were also proposed. The results indicated that to create compositions with high physical and mechanical characteristics, it is recommended to use a mixture of polyolefins containing 70% PE, modified by ultrasonic treatment.
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超声曝光对聚烯烃熔体的影响
本研究旨在探讨超声(US)效应对不同黏度聚合物混合物结构和性能的影响。值得注意的是,在目前的研究中,选择了不同品牌的聚丙烯和高压聚乙烯。对不同成分的高分子复合材料(PCM)进行了超声处理和不超声处理。建立了聚烯烃组成物的相结构对聚合物体系组成和粘度的依赖关系。测定了改性聚烯烃混合物的“结构-性能”规律。讨论了超声波对聚烯烃混合物结构恢复过程和新化学键形成的影响。提出了聚合物组成的结构及其加工工艺条件,使其具有较高的物理力学性能。结果表明,为了制造具有高物理和机械性能的组合物,建议使用含有70% PE的聚烯烃经超声处理改性的混合物。
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来源期刊
Eurasian Chemical Communications
Eurasian Chemical Communications CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
3.00
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0.00%
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