Flame behaviour of magnesium and aluminium hydroxide-filled polymer composites used in power and telecom cables

IF 1.2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Plastics, Rubber and Composites Pub Date : 2021-08-04 DOI:10.1080/14658011.2021.1962617
Elena Roda, Franco Galletti, A. Truscello, C. Gambarotti
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引用次数: 2

Abstract

ABSTRACT The effect of flame contact on Low Smoke Zero Halogen (LS0H) polyethylene-based model composite used for power cable has been investigated, focusing the attention on the fate of aluminium trihydroxide (ATH) and magnesium dihydroxide (MDH) utilized as flame retardant fillers. By using a flame reproducing the calorific value of EU CPR Regulation, during the contact with flame, the composite with magnesium hydroxide shows the formation of intermediate carbonate, which further decomposes giving the oxide. The same finding was observed in the blank test performed on pure MDH. This feature was not observed in ATH composite and pure one. The higher decomposition temperature of MDH, together with the formation of carbonate could play a key role in the higher efficiency of MDH compared to that of ATH. Moreover, we report that the stearic acid, present in the composite as compatibiliser and as processing aid, seems to migrate towards the external surfaces.
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电力和电信电缆用镁和氢氧化铝填充聚合物复合材料的燃烧性能
研究了火焰接触对电力电缆用低烟无卤聚乙烯基模型复合材料(LS0H)的影响,重点研究了作为阻燃填料的三氢氧化铝(ATH)和二氢氧化镁(MDH)的性能。通过使用火焰再现欧盟CPR法规的热值,在与火焰接触期间,与氢氧化镁的复合材料显示中间碳酸盐的形成,其进一步分解产生氧化物。在对纯MDH进行的空白试验中也观察到同样的结果。在ATH复合材料和纯ATH中没有观察到这一特征。MDH较高的分解温度和碳酸盐的形成是MDH比ATH效率更高的关键原因。此外,我们报告硬脂酸,作为增容剂和加工助剂存在于复合材料中,似乎向外表面迁移。
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来源期刊
Plastics, Rubber and Composites
Plastics, Rubber and Composites 工程技术-材料科学:复合
CiteScore
4.10
自引率
0.00%
发文量
24
审稿时长
4 months
期刊介绍: Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.
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